Solubilization rates of oils in surfactant solutions and their relationship to mass transport in emulsions.

Information on solubilization rates of oils in aqueous micellar solutions is reviewed. For ionic surfactants electrostatic repulsion prevents close approach of micelles to the oil-water interface, so that solubilization results from oil molecules dissolving individually in the solution and being taken up by micelles during and/or after transport across a diffusion boundary layer to the bulk solution. Experiments with SDS solutions and single oil drops having low (but not negligible) solubility indicate that mass transfer is often not rate-controlling.

Vorticity alignment and negative normal stresses in sheared attractive emulsions.

Attractive emulsions near the colloidal glass transition are investigated by rheometry and optical microscopy under shear. We find that (i) the apparent viscosity eta drops with increasing shear rate, then remains approximately constant in a range of shear rates, then continues to decay; (ii) the first normal stress difference N1 transitions sharply from nearly zero to negative in the region of constant shear viscosity; and (iii) correspondingly, cylindrical flocs form, align along the vorticity, and undergo a log-rolling movement. An analysis of the interplay between steric constraints, attractive forces, and composition explains this behavior, which seems universal to several other complex systems.

Enhanced characterization of oilfield emulsions via NMR diffusion and transverse relaxation experiments.

The procedure proposed by Packer and Rees (J. Colloid Interface Sci. 40 (1972) 206) to interpret pulsed field gradient spin-echo (PGSE) experiments on emulsions is commonly used to resolve for the distribution of droplet sizes via nuclear magnetic resonance (NMR).