Ba/Ti MOF: A Versatile Heterogeneous Photoredox Catalyst for Visible-Light Metallaphotocatalysis.

The field of sustainable heterogeneous catalysis is evolving rapidly, with a strong emphasis on developing catalysts that enhance efficiency. Among various heterogeneous photocatalysts, metal-organic frameworks (MOFs) have gained significant attention for their exceptional performance in photocatalytic reactions. In this context, contrary to the conventional homogeneous iridium or ruthenium-based photocatalysts, which face significant challenges in terms of availability, cost, scalability, and recyclability, a new Ba/Ti MOF (ACM-4) is developed as a heterogeneous catalyst that can mimic/outperform the conventional photocatalysts, offering a more sustainable solution for efficient chemical processes.

Ammonia Decomposition via MOF-Derived Photothermal Catalysts.

Three cobalt-based metal-organic framework (MOF)-derived catalysts were developed for photothermal hydrogen production via ammonia decomposition. The selected MOFs were from distinct families, featuring carboxylate and imidazole linkers, and diverse in terms of porosity. The resulting catalysts consisted of uniform and homogeneously dispersed cobalt nanoparticles embedded within a carbon matrix.

Leaching in Specific Facets of ZIF-67 and ZIF-L Zeolitic Imidazolate Frameworks During the CO Cycloaddition with Epichlorohydrin.

Zeolitic imidazolate frameworks (ZIFs) have been profusely used as catalysts for inserting CO into organic epoxides (i.e., epichlorohydrin) through cycloaddition.

Band Engineering of Semiconducting Microporous Graphitic Carbons by Phosphorous Doping: Enhancing of Photocatalytic Overall Water Splitting.

Carbon-based solar photocatalysts for overall water splitting could provide H as an energy vector in a clean and sustainable way. Band engineering to align energy levels can be achieved, among other ways, by doping. Herein, it is shown that phosphorous doping of microporous graphitic carbons derived from pyrolysis of α-, β-, and γ-cyclodextrin increases the valence band edge energy of the material, and the energy value of the conduction band decreases with the P content.

A reliable procedure for the preparation of graphene-boron nitride superlattices as large area (cm × cm) films on arbitrary substrates or powders (gram scale) and unexpected electrocatalytic properties.

Herein, a reliable procedure for the preparation of graphene-boron nitride superlattices, either as films or powders, consisting of the pyrolysis at 900 °C of polystyrene embedded pre-formed boron nitride single sheets is reported. The procedure can serve to prepare large area films (cm × cm) of this superlattice on quartz, copper foil and ceramics. Selected area electron diffraction patterns at every location on the films show the occurrence of the graphene-boron nitride superlattice all over the film.

Polystyrene as Graphene Film and 3D Graphene Sponge Precursor.

Polystyrene as a thin film on arbitrary substrates or pellets form defective graphene/graphitic films or powders that can be dispersed in water and organic solvents. The materials were characterized by visible absorption, Raman and X-ray photoelectron spectroscopy, electron and atomic force microscopy, and electrochemistry. Raman spectra of these materials showed the presence of the expected 2D, G, and D peaks at 2750, 1590, and 1350 cm, respectively.