Early Evidence of Shifts in Alpine Summit Vegetation: A Case Study From Kashmir Himalaya.

Under the contemporary climate change, the Himalaya is reported to be warming at a much higher rate than the global average. However, little is known about the alpine vegetation responses to recent climate change in the rapidly warming Himalaya. Here we studied vegetation dynamics on alpine summits in Kashmir Himalaya in relation to measured microclimate.

Stimuli-Responsive Naphthalene Diimide as Invisible Ink: A Rewritable Fluorescent Platform for Anti-Counterfeiting.

Herein, we report an approach to combat counterfeiting and storage of valuable information based on the solid-state fluorescence switching behavior of isoniazid functionalized naphthalene diimide (ISO_NDI) in response to an external stimuli (i. e., HCl vapor).

Conjugated Polymer-Based Electrical Sensor for Ultratrace Vapor-Phase Detection of Nerve Agent Mimics.

Considering the vital need to strengthen the national security emanating from chemical threats, a low-cost, portable ultrasensitive electrical sensor for real-time monitoring of diethylchlorophosphate (DCP) (nerve gas mimic) has been developed. The device consists of a "simple to be fabricated" two-terminal resistor and an electronic combinational circuit for rapid onsite detection of lethal nerve gas vapors with high degree of accuracy in milliseconds. This device is a smart readout electronic model that detects ultratrace DCP vapors by bright visual alerts from light-emitting diode (LED) and loud alarm signal without the need for employing a sophisticated instrument.

Fluorescence Resonance Energy Transfer-Based Wash-Free Bacterial Imaging and Antibacterial Application Using a Cationic Conjugated Polyelectrolyte.

The increase in bacterial infection and antibiotic resistance has posed a severe threat to the human health. This threat has warranted an imperative demand for the development of a new and effective bactericidal material to eradicate the antibiotic-resistant pathogenic bacteria. In this work, we report the wash-free imaging of Staphylococcus aureus (Gram-positive) and Escherichia coli (Gram-negative) bacteria using cationic conjugated polyelectrolyte[9,9-bis(6'-methylimidazoliumbromide)hexyl-fluorene- co-4,7-(2,1,3-benzothiadiazole)] (PFBT-MI) based on aggregation-induced fluorescence resonance energy transfer (FRET).

Development of Well-Preserved, Substrate-Versatile Latent Fingerprints by Aggregation-Induced Enhanced Emission-Active Conjugated Polyelectrolyte.

The development of highly efficient latent fingerprint (LFP) technology remains extremely vital for forensic and criminal investigations. In this contribution, a straightforward, rapid, and cost-effective method has been established for the quick development of well-preserved latent fingerprint on multiple substrates, including plastic, glass, aluminum foil, metallic surfaces, and so forth, without any additional treatment, based on aggregation-induced enhanced emission-active conjugated polyelectrolyte (CPE) 3,3'-((2-(4-(1,2-diphenyl-2-(p-tolyl)vinyl)phenyl)-7-(7-methylbenzo[c][1,2,5]thiadiazol-4-yl)-9H-fluorene-9,9-diyl)bis(hexane-6,1-diyl))bis(1-methyl-1H-imidazol-3-ium) bromide, revealing clearly the third-level details (ridges, bifurcations, and pores) with high selectivity, high contrast, and no background interference even by blood stains, confirming the ability of the proposed technique for LFP detection with high resolution. The LFP development process was accomplished simply by immersing fingerprint-loaded substrate into the CPE solution for ∼1 min, followed by shaking off the residual polymer solution and then air drying.

Conjugated Polyelectrolyte Based Sensitive Detection and Removal of Antibiotics Tetracycline from Water.

A new conjugated polyelectrolyte poly[5,5'-(((2-phenyl-9H-fluorene-9,9-diyl)bis(hexane-6,1-diyl))bis(oxy))diisophthalate] sodium (PFPT) was synthesized via the palladium-catalyzed Suzuki cross-coupling polymerization method and successfully applied for the rapid, real time, and highly sensitive detection of antibiotics tetracycline (Tc) in 100% aqueous media via photoinduced electron transfer with detection limit in the ppb level. Remarkably, PFPT could also be applied for the trace analysis of Tc in serum samples having recoveries well in the range 92-97% with relative standard deviations (RSD) of 1.01-1.

Anion-Exchange Induced Strong π-π Interactions in Single Crystalline Naphthalene Diimide for Nitroexplosive Sensing: An Electronic Prototype for Visual on-Site Detection.

A new derivative of naphthalene diimide (NDMI) was synthesized that displayed optical, electrical, and visual changes exclusively for the most widespread nitroexplosive and highly water-soluble toxicant picric acid (PA) due to strong π-π interactions, dipole-charge interaction, and a favorable ground state electron transfer process facilitated by Coulombic attraction. The sensing mechanism and interaction between NDMI with PA is demonstrated via X-ray diffraction analysis, (1)H NMR studies, cyclic voltammetry, UV-visible/fluorescence spectroscopy, and lifetime measurements. Single crystal X-ray structure of NDMI revealed the formation of self-assembled crystalline network assisted by noncovalent C-H···I interactions that get disrupted upon introducing PA as a result of anion exchange and strong π-π stacking between NDMI and PA.

FRET-assisted selective detection of flavins via cationic conjugated polyelectrolyte under physiological conditions.

Flavins viz. riboflavin (RF, vitamin B), flavin mononucleotide (FMN) and flavin adenine dinucleotide (FAD) represent an important class of biomolecules ubiquitously found in living systems that are vital for numerous cellular activities inside the body. The fluorescence amplified detection of these flavins at ppb levels is achieved for the first time using water soluble cationic conjugated polymer PMI under physiological conditions.

Aggregation-Induced FRET via Polymer-Surfactant Complexation: A New Strategy for the Detection of Spermine.

A new water-soluble cationic conjugated polymer [9,9-bis(6'-methyl imidazolium bromide)hexyl)fluorene-co-4,7-(2,1,3-benzothiadiazole)] (PFBT-MI) was designed and synthesized via Suzuki cross-coupling polymerization in good yields without any tedious purification steps. PFBT-MI showed excellent photophysical responses toward SDS and SDBS with a detection limit of 0.12 μM/(34 ppb) and 0.

Conjugated Polymer Nanoparticles for the Amplified Detection of Nitro-explosive Picric Acid on Multiple Platforms.

Spontaneously formed conjugated polymer nanoparticles (CPNs) or polymer dots displayed remarkable fluorescence response toward nitroexplosive-picric acid (PA) in multiple environments including 100% aqueous media, solid support using portable paper strips and vapor phase detection via two terminal device. This new cationic conjugated polyelectrolyte (CPE) poly(3,3'-((2-phenyl-9H-fluorene-9,9-diyl)bis(hexane-6,1-diyl))bis(1-methyl-1H-imidazol-3-ium)bromide) (PFMI) was synthesized by Suzuki coupling polymerization followed by post functionalization method without employing any hectic purification technique. Highest quenching constant value (K(sv)) of 1.

Ultrasensitive detection of nitroexplosive - picric acid via a conjugated polyelectrolyte in aqueous media and solid support.

Picric acid (PA) detection at parts per trillion (ppt) levels is achieved by a conjugated polyelectrolyte (PMI) in 100% aqueous media and on a solid platform using paper strips and chitosan (CS) films. The unprecedented selectivity is accomplished via combination of ground state charge transfer and resonance energy transfer (RET) facilitated by favorable electrostatic interactions.

Cytomictic anomalous male meiosis and 2n pollen grain formation in Mertensia echioides Benth. (Boraginaceae) from Kashmir Himalaya.

Presently Mertensia echioides Benth. (Boraginaceae) collected from Kashmir Himalaya, India, is cytologically analyzed for the first time revealing 2n = 2x = 24 (diploid). Interestingly we found 4.