The rapid development of nanotechnology and materials science has led to remarkable advances in sensor applications across various fields [...
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
January 2025
Improving the ease of operation and portability of hydrogen peroxide (HO) detection in daily production and life holds significant application value. However, it remains a challenge to achieve rapid colorimetric detection of HO and color change quantification. In this study, we achieved rapid and visual detection of HO by MoOx (2 ≤ x ≤ 3) nanoparticles with rich oxygen vacancies using machine vision.
View Article and Find Full Text PDFThe wide utilization of lithium-ion batteries (LIBs) prompts extensive research on the anode materials with large capacity and excellent stability. Despite the attractive electrochemical properties of pure Si anodes outperforming other Si-based materials, its unsafety caused by huge volumetric expansion is commonly admitted. Silicon monoxide (SiO) anode is advantageous in mild volume fluctuation, and would be a proper alternative if the low initial columbic efficiency and conductivity can be ameliorated.
View Article and Find Full Text PDFMolybdenum trioxide (MoO) is an attractive semiconductor. Thus, bandgap engineering toward photoelectronic applications is appealing yet not well studied. Here, we report the incorporation of sulfur atoms into MoO, using sulfur powder as a source of sulfur, via a self-developed hydrothermal synthesis approach.
View Article and Find Full Text PDFDue to the depletion of the global ozone layer and the presence of ozone holes, humans are increasingly exposed to threats from solar ultraviolet radiation. Therefore, researching and developing a highly selective, sensitive, simple, and fast ultraviolet sensor is of significant importance for personal protection. In recent years, new nanomaterials have shown good application prospects in the research of ultraviolet sensors.
View Article and Find Full Text PDFEthnopharmacological Relevance: Ginkgo biloba L. (Ginkgoaceae), a traditional Chinese medicine, has been applied for thousands of years for the treatment of cardio-cerebral vascular diseases in China. It is written in Compendium of Materia Medica that Ginkgo has the property of "dispersing poison", which is now referred to as anti-inflammatory and antioxidant.
View Article and Find Full Text PDFNanomaterials (Basel)
November 2021
Photochromic materials have attracted increasing attention. Here, we report a novel photo-reversible color switching system based on oxygen-vacancy-engineered MoO nanostructures with water/N-methyl-2-pyrrolidone (NMP) as solvents. In this work, the system rapidly changed from colorless to blue under UV irradiation (360-400 nm) and slowly recovered its colorless state under visible light irradiation.
View Article and Find Full Text PDFFirst-row non-precious metal-based catalysts are widely studied and recognized as potential substitutes for precious metal-based catalysts in the oxygen evolution reaction (OER) for hydrogen generation but their application remains challenging. In this study, a unique class of Co-Fe selenide hollow nanospheres (CoSe@FeSe2) is well-designed through a facile hydrothermal method. The in situ formed hybrid composites possess numerous interfaces allowing partial electron transfer via O2- bridges to optimize the adsorption feature of the reaction intermediates, *OH, *O, and *OOH, on the catalysts.
View Article and Find Full Text PDFGiant cell tumor of tendon sheath (GCTTS) is characterized by diffuse proliferation of synovial-like cells and multinucleated giant cells along tendon sheaths. This benign tumor typically presents in the third to fourth decade of life and is exceeding rare in children. Here we describe a case of a 10-years-old girl with a history of soft tissue swelling involving the third digit of left hand, bilateral wrists and ankles.
View Article and Find Full Text PDFArch Dermatol Res
July 2020
The main pathology involved in chronic idiopathic urticaria (CIU) is immunological dysfunction which mainly adapts to the immune system of body. Pseudomonas aeruginosa-mannose-sensitive hemagglutinin (PA) is an inactivated Pseudomonas aeruginosa biological product which displays a broad immune regulatory effect. The current study was designed to explore the protective nature of PA as an immune regulator in CIU.
View Article and Find Full Text PDFMercury ions can significantly affect the organism and environment even at a very low concentration. Thus, great efforts have been devoted to developing high sensitive electrochemical sensors, especially the one that not only detect the mercury ions but also effective sensitive to thymine-Hg-thymine in aqueous solution. Metal-organic-frameworks (MOFs) possess hollow nature and are easy for grafting functional groups, however, there is still no attempts for working as electrochemical sensors in detecting mercury ions.
View Article and Find Full Text PDFThe identification of plant species not only is a hobby but also has important application value in plant resources science. Traditional plant identification often relies on the experience of botanists. The infrageneric identification of plants is easily mistaken due to similarities in organ features.
View Article and Find Full Text PDFThe authors of "A glassy carbon electrode modified with N-doped carbon dots for improved detection of hydrogen peroxide and paracetamol (Microchimica Acta 185, no. 2 (2018): 87)" wish to replace the incorrect images of Fig. 1C, 1D shown below.
View Article and Find Full Text PDFIn view of the easy control and contactless spatial nature of light, the photoreversible color switching system has attracted tremendous attention. Although some progress has been achieved in the past few years, the practical applications have been limited by the complicated preparation process, material toxicity and low reaction yield. Herein, we report a rapid, a one-pot large-scale synthesis approach for the preparation of carbon dots (CDs)/TiO nanocomposites the thermal condensation at 160 °C, affording high photocatalytic color switching on/off performance.
View Article and Find Full Text PDFSo far, a large number of rare earth (RE) and non-RE-doped emission-tunable crystals based on controllable energy transfer have become available, but numerous mechanistic issues, particularly for those that involve temperature-dependent energy transfer between the well-shielded 4f RE ions, lack comprehensive theoretical and experimental investigation, limiting greatly their development and applications in the future. Here, we design and report a type of Tb,Eu-doped SrAlOCl phosphors capable of multiemissions upon excitation at 376 nm, through using the orthorhombic SrAlOCl as the host lattice while the well-shielded 4f Tb and Eu ions as dual luminescent centers. Our results reveal that the energy transfer from Tb to Eu ions, happening via an electric dipole-quadrupole (d-q) interaction, can be controlled by the doping ratio of Tb and Eu, leading to the tunable emissions from green (0.
View Article and Find Full Text PDFBiosens Bioelectron
November 2018
Graphene-embedded plant tissues show a high sensitivity to electrochemical signals, which enables a screen-printed electrode to be used for electrochemical fingerprint recording. The electrochemical fingerprints obtained under different conditions can be transformed into multidimensional recognition modes for plant identification. These electrochemical fingerprints reflect the types and quantities of the electrochemically active substances in plant tissues such that the fingerprints can be used for chemotaxonomic investigations.
View Article and Find Full Text PDFNitrogen doped carbon dots (NCDs) were synthesized using a low temperature approach and used to modify a glassy carbon electrode (GCE) via dipping. The oxygen groups on the surface of the NCDs, and the charge delocalization of the NCDs warrant an excellent electrocatalytic activity of the GCE toward oxidation of paracetamol (PA) and reduction of HO. PA and HO were detected at 0.
View Article and Find Full Text PDFA simple water immersing treatment has been established for regulating the electrocatalytic activity of commercial graphene ink. This process enables to remove additives in graphene ink and consequently expose the surface defects. A graphene ink coated glass has been fabricated as an example platform for simultaneous determination of ascorbic acid (AA), dopamine (DA), and uric acid (UA).
View Article and Find Full Text PDFA chitosan based hydrogel has been fabricated using silver ions as crosslinking agent. Silver redox behavior in the hydrogel is suppressed due to complexation. However, hydrogen peroxide induced hydroxyl radicals could attract the glucoside bonds and consequently restore silver redox behavior.
View Article and Find Full Text PDFShanghai Kou Qiang Yi Xue
October 2016
Purpose: To prepare Koukuining granules and observe its efficiency in the treatment of recurrent aphthas ulce (RAU).
Methods: In accordance with the theories of traditional Chinese medicine, the prescriptions of Koukuining granules were composed of rhizoma coptidis, radix scutellariae and other Chinese herbs, and the preparation procedure was conducted by means of wet granulation technology. One hundred patients with RAU were randomly divided into experimental group and control group equally.
The graphitic carbon nitride (g-CN) which is a two-dimensional conjugated polymer has drawn broad interdisciplinary attention as a low-cost, metal-free, and visible-light-responsive photocatalyst in the area of environmental remediation. The g-CN-based materials have excellent electronic band structures, electron-rich properties, basic surface functionalities, high physicochemical stabilities and are "earth-abundant." This review summarizes the latest progress related to the design and construction of g-CN-based materials and their applications including catalysis, sensing, imaging, and white-light-emitting diodes.
View Article and Find Full Text PDFGraphene based nanocomposites are receiving increasing attention in many fields such as material chemistry, environmental science and pharmaceutical science. In this study, a facial synthesis of a reduced graphene oxide-silver nanocomposite (RGO-Ag) was carried out from Plectranthus amboinicus leaf extract. The synthesized nanocomposite was characterized by using X-ray diffraction, scanning electron microscope, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, transmission electron microscope and UV-vis spectroscopy for structural confirmation.
View Article and Find Full Text PDFPhotovoltachromic cells (PVCCs) are of great interest for the self-powered smart windows of architectures and vehicles, which require widely tunable transmittance and automatic color change under photostimuli. Organolead halide perovskite possesses high light absorption coefficient and enables thin and semitransparent photovoltaic device. In this work, we demonstrate co-anode and co-cathode photovoltachromic supercapacitors (PVCSs) by vertically integrating a perovskite solar cell (PSC) with MoO3/Au/MoO3 transparent electrode and electrochromic supercapacitor.
View Article and Find Full Text PDFA novel poly (diallyldimethylammonium chloride) functionalized reduced graphene oxide (PDDA-RGO) nanocomposite modified electrode was fabricated, and applied for the electrochemical determination of quinoline yellow (QY). The formation of PDDA-RGO nanocomposite was confirmed by SEM, FTIR and Raman spectroscopy. The electrocatalytic activity of PDDA-RGO nanocomposite to the oxidation of QY was evaluated using cyclic voltammetry and differential pulse voltammetry.
View Article and Find Full Text PDFBackground: Baicalein, a specific lipoxygenase (LOX) inhibitor, has anti-inflammatory and antioxidant effects. However, the functional role of baicalein in angiotensin II (Ang II)-induced hypertension and cardiac remodeling remains unclear. Here we investigated the effect of baicalein on cardiac hypertrophy and fibrosis and the underlying mechanism.
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