Lignin-based monophenolic model compounds in L-tyrosine derivative synthesis via tyrosine phenol lyase.

Tyrosine phenol lyase (TPL) synthesises L-tyrosine derivatives from monophenols, pyruvate and ammonia. Production of such high-value aromatic chemicals from biomass-derived raw materials is of great interest. In this study, six monophenols (guaiacol, phenol, o-cresol, m-cresol, catechol and syringol) were chosen based on the structure of lignin and were studied as substrates in the enzymatic reaction.

Do personality profiles contribute to patterns of physical activity and sedentary behavior in adulthood? A prospective cohort study.

Background: Despite the observed associations of personality traits with levels of moderate-to-vigorous physical activity (MVPA) and sedentary behavior (SB), studies exploring whether the personality profiles differ in terms of the pattern of accumulation of physical behavior are lacking. The aim of this study was to identify adults' personality profiles and to characterize and investigate how these profiles differ in physical behavior.

Methods: The study utilized the longitudinal data of the participants of the Jyväskylä Longitudinal Study of Personality and Social Development (n = 141-307).

Pregnancy risk in beef and dairy cows after supplementing semen with transforming growth factor beta-1 at the time of artificial insemination.

Our objective was to determine if the addition of a concentrated human recombinant transforming growth factor beta-1 (TGF) to bovine semen at the time of AI would result in increased risk of pregnancy in beef and dairy cows. Suckled beef cows (n = 1,132) in 11 herds across 2 states and lactating dairy cows (n = 2,208) in one organic-certified herd were enrolled. Beef cows received fixed-time AI (FTAI) following a 7 d CO-Synch + controlled internal drug release estrous synchronization protocol.

Stability in health behavior patterns in middle adulthood: a 19-year follow-up study.

This study investigated subgroups of adults with particular health behavior patterns, their stability over 19 years, and the role of sociodemographic and personality characteristics in these. Data on smoking, alcohol consumption, and physical activity were collected at ages 42, 50, and 61 in the Jyväskylä Longitudinal Study of Personality and Social Development ( = 205-302). Latent class, latent transition, and logistic regression analyses were used.

Child socioemotional behavior and adult temperament as predictors of physical activity and sedentary behavior in late adulthood.

Background: Most studies investigating the association of temperament with physical activity and sedentary behavior have examined children or adolescents, employed cross-sectional or longitudinal designs that do not extend from childhood into adulthood, and utilized self- or parent-reported data on physical activity and sedentary behavior. This longitudinal study investigated whether socioemotional behavior in childhood and temperament in middle adulthood predict accelerometer-measured physical activity and sedentary behavior in late adulthood.

Methods: This study was based on the Jyväskylä Longitudinal Study of Personality and Social Development (JYLS).

Climate and biodiversity impacts of low-density polyethylene production from CO and electricity in comparison to bio-based polyethylene.

Plastics are essential materials for modern societies, but their production contributes to significant environmental issues. Power-to-X processes could produce plastics from captured CO and hydrogen with renewable electricity, but these technologies may also face challenges from environmental perspective. This paper focuses on environmental sustainability assessment of CO-based low-density polyethylene (LDPE) compared to bio-based LDPE.

Highly effective fractionation chemistry to overcome the recalcitrance of softwood lignocellulose.

The efficient fractionation and thus production of individual biomass components are pivotal processes in the biorefinery concept. However, the recalcitrant nature of lignocellulose biomass, especially in the case of softwood, is one of the main obstacles to the wider application of biomass-based chemicals and materials. In this study, the use of aqueous acidic systems in the presence of thiourea was studied for the fractionation of softwood in mild conditions.

Epidemiology and management of proximal tibia fractures in children and adolescents: a population-based study based on the Kids' Fracture Tool.

Background And Purpose: Proximal tibial fractures are infrequent injuries in children, and the literature on epidemiology, associated injuries, and management is limited. We calculated a population-based incidence and described the characteristics of proximal tibial fractures in children in terms of complications and management.

Patients And Methods: This is a retrospective study over a 6-year-period during including 241 children with proximal tibial fractures who presented to our university hospital.

Usefulness of the Parental Electronic Diary During Medical Rounds in a NICU.

Parental involvement in the care of their baby in family rooms in neonatal intensive care units (NICUs) can be improved. This could be done with an electronic medical report completed by the parents, which is then linked to the patient record system. The parents selected for this study completed an electronic diary during their stay in the NICU, while the staff answered a questionnaire about their opinion on the usefulness of the parents' diary.

High-purity lignin fractions and nanospheres rich in phenolic hydroxyl and carboxyl groups isolated with alkaline deep eutectic solvent from wheat straw.

A combined pretreatment based on alkaline deep eutectic solvent (DES) of KCO and glycerol and sequential acid fractionation was developed to extract reactive lignin from wheat straw biomass. This process exhibited excellent purification performance in lignin isolation, and the lignin fractionated at low pH displayed high reactivity, having hydroxyl and carboxyl groups up to 9.60 and 2.

Modification of face masks with zeolite imidazolate framework-8: A tool for hindering the spread of COVID-19 infection.

The worldwide spread of the SARS-CoV-2 virus has continued to accelerate, putting a considerable burden on public health, safety, and the global economy. Taking into consideration that the main route of virus transmission is via respiratory particles, the face mask represents a simple and efficient barrier between potentially infected and healthy individuals, thus reducing transmissibility per contact by reducing transmission of infected respiratory particles. However, long-term usage of a face mask leads to the accumulation of significant amounts of different pathogens and viruses onto the surface of the mask and can result in dangerous bacterial and viral co-infections.

Aqueous phase reforming of birch and pine hemicellulose hydrolysates.

The current work focuses on studying the aqueous phase reforming (APR) of pine and birch hydrolysate obtained from waste wood by using organic acids available from biorefineries. Processing of representative synthetic mixtures was utilized in the work in order to support data interpretation related to the influence of different chemical compound and processing parameters on the APR of the actual hydrolysates. It was shown, that hydrogenation of the hydrolysates prior to APR was not feasible in the presence of formic acid, which ruled out one potential processing route.

A Qualitative Investigation Into Faith and LGBTQ Identities in a Nonclinical Sample of Readers of the Dear Abby Column: The Dear Abby Project.

To better understand the relationship between faith and LGBTQ+ identity, we conducted a qualitative analysis of 86 respondents to a general question posed through the Dear Abby column. Responses were anonymized and analyzed using a grounded theory approach. Analysis revealed six themes, reflecting a diversity of lived experience from community rejection to acceptance, and self-rejection to feelings of acceptance by God.

Evaluation of biological and economic efficiency of the All Heifer, No Cow beef production system using a system dynamics model based on 6 yr of demonstration herd data.

Alternative management strategies with no cows and all heifers may improve biological and economic efficiency of beef production. The All Heifer, No Cow (AHNC) beef production system involves insemination of nulliparous heifers with female sex-selected semen (FSS) to produce primarily female calves that are early weaned at 3 mo of age. Dams are finished on a high concentrate diet and harvested before 30 mo of age.

Comparison of Lignin Fractions Isolated from Wheat Straw Using Alkaline and Acidic Deep Eutectic Solvents.

This study aims to examine the characteristics of two solid lignin fractions isolated from wheat straw using alkaline and acidic deep eutectic solvents (DESs). The chemical properties and morphological characteristics of the two lignin fractions were evaluated by measuring their purity, elemental composition, molecular weight and particle size distributions, and microstructure. Their chemical structure was evaluated using DRIFT (diffuse reflectance infrared Fourier transform) spectroscopy, GPC (gel permeation chromatography), TGA (thermogravimetric analysis), C NMR (nuclear magnetic resonance), P NMR, and HSQC NMR.

Evaluation of performance and carcass traits for a five-cohort All Heifer, No Cow beef production system demonstration herd.

The All Heifer, No Cow (AHNC) beef production system is an alternative to conventional cow/calf production that involves insemination of nulliparous heifers with sexed semen to produce female calves that are early weaned at 3 mo of age. Dams are finished on a high-concentrate diet and harvested before reaching 30 mo of age. Objectives of this research were to document reproductive, feedyard, calf, and carcass performance of an AHNC herd; evaluate effects of carcass maturity on carcass quality; and determine if performance of initial cohorts (i.

Intraobserver and interobserver reliability of mud scoring systems for use in cattle at slaughter.

At slaughter plants, live cattle are often scored for mud coverage as mud on hides can impact food safety and drives decisions regarding interventions during processing. Currently, there is no standardized method utilized to assess mud coverage. The aim of this study was to determine the intraobserver and interobserver reliability of 3, 4, and 5 point mud scoring systems.

Gas phase methanol synthesis with Raman spectroscopy for gas composition monitoring.

Applicability of Raman spectroscopy for time-resolved gas composition monitoring during direct methanol synthesis carbon dioxide hydrogenation was investigated. A series of methanol synthesis experiments with varied reactor conditions was conducted and the reactor outlet stream was analyzed with in-line gas Raman spectroscopy. Concentrations of H, CO and CO were determined directly from the acquired spectral data.

Evaluation of intramuscular injection of oxytetracycline for use as an experimental model to induce pain and assess the efficacy of pain mitigation strategies in dairy cows.

Objective: To evaluate IM injection of oxytetracycline as an experimental model to induce pain and assess the analgesic efficacy of flunixin meglumine (FM) in dairy cows.

Animals: 15 healthy nonlactating Jersey (n = 10) and Holstein (5) cows.

Procedures: In the first of 2 experiments, 5 Jerseys were administered oxytetracycline (10 mg/kg, IM), divided between the right side of the neck and left hind limb.

Dairy producer perceptions of the Farmers Assuring Responsible Management (FARM) Animal Care Program.

Dairy farms producing 98% of the US milk supply participate in the Farmers Assuring Responsible Management (FARM) Animal Care Program. Producers who sell milk to cooperatives or processors participating in FARM must follow program standards. The objectives of this study were to assess producer perceptions about the knowledge, experience, and value of FARM and to determine whether perceptions differ based on demographics.

Electrode material studies and cell voltage characteristics of the in situ water electrolysis performed in a pH-neutral electrolyte in bioelectrochemical systems.

Hydrogen-oxidizing bacteria (HOB) have been shown to be promising micro-organisms for the reduction of carbon dioxide to a wide range of value-added products in bioelectrochemical systems with in situ water electrolysis of the cultivation medium, also known as a hybrid biological-inorganic systems (HBI). However, scaling up of this process requires overcoming the inherent constraints of the low energy efficiency partly associated with the pH-neutral electrolyte with low conductivity. Most of the research in the field is concentrated on the bacterial cultivation, whereas the analysis and evaluation of the electrode material performance have received little attention in the literature so far.

Two split-time artificial insemination programs in suckled beef cows.

Our objective was to determine which of 2 split-time AI programs applied to suckled beef cows would result in greater pregnancy risk. Suckled beef cows (n = 1,062) at 12 locations in 4 states (CO, KS, MY, and WA) were enrolled. Cows were treated on d -7 with a progesterone insert concurrent with 100 µg GnRH and on d 0 with 25 mg PGF plus removal of the insert.

Formic acid aided hot water extraction of hemicellulose from European silver birch (Betula pendula) sawdust.

Hemicellulose has been extracted from birch (Betula pendula) sawdust by formic acid aided hot water extraction. The maximum amount of hemicellulose extracted was about 70mol% of the total hemicellulose content at 170°C, measured as the combined yield of xylose and furfural. Lower temperatures (130 and 140°C) favored hemicellulose hydrolysis rather than cellulose hydrolysis, even though the total hemicellulose yield was less than at 170°C.

Using estrus detection patches to optimally time insemination improved pregnancy risk in suckled beef cows enrolled in a fixed-time artificial insemination program.

A multilocation study examined pregnancy risk (PR) after delaying AI in suckled beef cows from 60 to 75 h when estrus had not been detected by 60 h in response to a 7-d CO-Synch + progesterone insert (CIDR) timed AI (TAI) program (d -7: CIDR insert concurrent with an injection of GnRH; d 0: PGF injection and removal of CIDR insert; and GnRH injection at TAI [60 or 75 h after CIDR removal]). A total of 1,611 suckled beef cows at 15 locations in 9 states (CO, IL, KS, MN, MS, MT, ND, SD, and VA) were enrolled. Before applying the fixed-time AI program, BCS was assessed, and blood samples were collected.