A novel hydrogen bonded bimetallic supramolecular coordination polymer {[SnMe3(bpe)][Ag(CN)2] · 2H2O} as anticancer drug.

The reaction of Me(3)SnCl, K(3)[Ag(CN)(4)] and 1,2-bis(4-pyridyl)ethane (bpe) in water/CH(3)CN solution at room temperature affords the novel bimetallic supramolecular coordination polymer (SCP) {[SnMe(3)(bpe)] [Ag(CN)2] · 2H(2)O}(n), 1. The structure of 1 consists of cationic {-Sn(Me(3))-bpe-}(+) chains that are neutralized by [Ag(CN)(2)](-) anions. The dicyanoargentate(I) anions present discrete uncoordinated fragments between the cationic chains.

Kinetics and mechanism of the heterogeneous catalyzed oxidative decolorization of Acid-Blue 92 using bimetallic metal-organic frameworks.

The kinetics study of the oxidative decolorization of Acid-Blue 92 has been investigated by hydrogen peroxide catalyzed with bimetallic metal-organic frameworks. The used metal-organic frameworks (MOF) are [Ph3SnCu(CN)2·L] where L=pyrazine (pyz) 1, methylpyrazine (mepyz) 2, 4,4'-bipyridine (bpy) 3, trans-1,2-bis(4-pyridyl)ethene (tbpe) 4 or 1,2-bis(4-pyridyl)ethane (bpe) 5. The reaction was followed by conventional UV-Vis spectrophotometer at λmax=571 nm.