Structural features like 3D nano-size, ultrathin thickness and amorphous/crystalline interfaces play crucial roles in regulating charge separation and active sites of photocatalysts. However, their co-occurrence in a single catalyst and exploitation in photocatalytic CO reduction (PCR) remains challenging. Herein, nano-sized bismuth oxychloride spheres (BiOCl-NS) confining three-layered nanoplates (∼2.
View Article and Find Full Text PDF2,{2}',7,{7}'-Tetrakis(,-di--methoxyphenylamine)-9,{9}'-spiro-bi-fluorene(spiro-OMeTAD) has often been used as a hole-transporting material (HTM) in mesoscopic perovskite solar cells (PSCs). However, its potential applications are limited due to its poor conductivity of approximately 10 to 10 cm V s in pristine form, and this influences the stability and intrinsic hole conductivity of the device. In this work, a Mn complex [(Mn(Me-tpen)(ClO) )] is introduced as a p-dopant to improve the properties of spiro-OMeTAD-based PSCs, including the optical, electrical, conductivity, and stability properties.
View Article and Find Full Text PDFExploiting spontaneous polarization of ferroelectric materials to achieve high charge separation efficiency is an intriguing but challenging research topic in solar energy conversion. This work shows that loading high work function RuO cocatalyst on BiFeO (BFO) nanoparticles enhances the intrinsic ferroelectric polarization by efficient screening of charges to RuO via RuO /BFO heterojunction. This leads to enhancement of the surface photovoltage of RuO /BFO single nanoparticles nearly 3 times, the driving force for charge separation and transfer in photocatalytic reactions.
View Article and Find Full Text PDFObjective: To carry out a systematic review of the available studies on COVID-19 (coronavirus disease 2019) in neonates seen globally since the onset of the COVID-19 global pandemic in 2020. The paper also describes a premature baby with reverse transcription (RT)-PCR-positive COVID-19 seen at the Blackpool Teaching Hospitals NHS Foundation Trust, UK.
Design: We conducted a multifaceted search of the Cumulative Index to Nursing and Allied Health Literature, Embase, Medline and PubMed from 1 December 2019 to 12 May 2020 to harvest articles from medical journals and publications reporting cases of COVID-19 in neonates from anywhere in the world.
Screening of stable visible-light-responsive water oxidation semiconductor photocatalysts is highly desired for the development of photocatalytic water splitting systems. Herein, a visible-light-absorbing SrNiWO double perovskite oxide photocatalyst was successfully prepared via a conventional solid-state reaction method. The intrinsic SrNiWO shows photocatalytic oxygen evaluation reaction (OER) activity of 60 μmol h g, even without loading any cocatalysts.
View Article and Find Full Text PDFNitrite ions (NO ), as one of the important inorganic anions, exhibit considerable effects towards the environment and human health. Moreover, over intake of this anion may cause dangerous diseases. Herein, we successfully fabricated silver nanoparticles (AgNPs) using 4-amino-5-hydroxynaphthalene-2, 7-disulphonic acid monosodium salt (AHNDMS) and functionalized them with -aminobenzoic acid (PABA), and used the functionalised AgNPs as a sensitive and selective colorimetric sensor for nitrite ions.
View Article and Find Full Text PDFCloud computing has revolutionized healthcare in today's world as it can be seamlessly integrated into a mobile application and sensor devices. The sensory data is then transferred from these devices to the public and private clouds. In this paper, a hybrid and distributed environment is built which is capable of collecting data from the mobile phone application and store it in the cloud.
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