Biosorbent silver nanoparticles decorated coffee-ground waste composite for cleaning water and antimicrobial applications.

A sustainable biosorbent, silver nanoparticles-decorated coffee-ground waste (CWAg), was synthesized through a simple in-situ reduction method. CWAg is extensively characterized via SEM-EDX, PZC, FTIR, XRD, HR-TEM, and XPS analyses. The biosorbent was tested to remove chromium (Cr(VI)) and methylene blue (MB) from wastewater, and its antibacterial properties was evaluated.

Chemical, electrochemical, and quantum investigation into the use of an organophosphorus derivative to inhibit copper corrosion in acidic environments.

In order to protect the copper against corrosion, a novel corrosion inhibitor known as diphenyl ((2-aminoethyl) amino) (4-methoxyphenyl) methyl) phosphonate (DAMP) was developed. Acid solutions of HCl and HSO were the aggressive solutions employed in this study. Analysis using the FT-IR, H-NMR, P-NMR, C-NMR and BET confirmed that the DAMP was successfully synthesized.

Synthesis and molecular docking study of α-aminophosphonates as potential multi-targeting antibacterial agents.

Antibacterial compounds that reduce extracellular polymeric substances (EPS) are needed to avoid bacterial biofilms in water pipelines. Herein, green one-pot synthesis of α-aminophosphonates (α-Amp) [A-G] was achieved by using ionic liquid (IL) as a Lewis acid catalyst. The synthesized α-Amp analogues were tested against different bacteria such as Bacillus subtilis, Escherichia coli, and Pseudomonas aeruginosa.

Novel Corrosion Inhibitor for Carbon Steel in Acidic Solutions Based on α-Aminophosphonate (Chemical, Electrochemical, and Quantum Studies).

α-aminophosphonate (α-AP) is used as a novel corrosion inhibitor for carbon steel. The aggressive media applied in this study are HCl and HSO acid solutions. The findings indicate that the morphology of the α-AP compound is cubic, with particles ranging in size from 17 to 23 μm.

Mesoporous chitosan derivatives for effective uranyl sorption: Synthesis, characterization, and mechanism-application to ore leachate.

Two sorbents were developed from chitosan aminophosphonation: via one-pot process to produce aminophosphonated derivative (r-AP), followed by further pyrolysis to produce mesoporous improved biochar (IBC). Sorbents structures were elucidated using CHNP/O, XRD, BET, XPS, DLS, FTIR, and pH-titration. The IBC exhibits an improved specific surface (262.

Superparamagnetic Multifunctionalized Chitosan Nanohybrids for Efficient Copper Adsorption: Comparative Performance, Stability, and Mechanism Insights.

To limit the dangers posed by Cu(II) pollution, chitosan-nanohybrid derivatives were developed for selective and rapid copper adsorption. A magnetic chitosan nanohybrid (r-MCS) was obtained via the co-precipitation nucleation of ferroferric oxide (FeO) co-stabilized within chitosan, followed by further multifunctionalization with amine (diethylenetriamine) and amino acid moieties (alanine, cysteine, and serine types) to give the TA-type, A-type, C-type, and S-type, respectively. The physiochemical characteristics of the as-prepared adsorbents were thoroughly elucidated.

Diagnosis of subtle syndesmotic instability using conventional CT-imaging and axial force in different foot positions.

Background: Currently, there is no available method that can objectively and reliably detect subtle instability of the distal tibiofibular joint. The purpose of this study is to diagnose, using computerized axial tomography and an adjustable simulated loading device, subtle instability of the tibiofibular syndesmosis.

Methods: Fifteen healthy individuals and 15 patients with clinical suspicion of subtle instability of the tibiofibular syndesmosis (total 60 ankles) were studied using an adjustable simulated loading device (ASLD).

Mesoporous Magnetic Cysteine Functionalized Chitosan Nanocomposite for Selective Uranyl Ions Sorption: Experimental, Structural Characterization, and Mechanistic Studies.

Nuclear power facilities are being expanded to satisfy expanding worldwide energy demand. Thus, uranium recovery from secondary resources has become a hot topic in terms of environmental protection and nuclear fuel conservation. Herein, a mesoporous biosorbent of a hybrid magnetic-chitosan nanocomposite functionalized with cysteine (Cys) was synthesized via subsequent heterogeneous nucleation for selectively enhanced uranyl ion (UO) sorption.

Facile Synthesis of ZnS/1T-2H MoSnanocomposite for Boosted adsorption/photocatalytic degradation of methylene blue under visiblelight.

Facile solvothermal techniques were used to manufacture ZnS/1T-2H MoS nanocomposite (ZMS) with outstanding adsorption-photocatalytic activity. The formed catalyst was characterized by different tools; XRD, HR-TEM, EDX, FTIR, Raman, Nadsorprion/desorption, Zeta potential, PL,and XPS. The analysis provided the formation on mixed phase of metallic 1Tand 2H phases.

Mechanistic study of Hg(II) interaction with three different α-aminophosphonate adsorbents: Insights from batch experiments and theoretical calculations.

Herein, efficient and potential chelating α-aminophosphonate based sorbents (AP-) derived from three different amine origins (aniline/anthranilic acid/O-phenylenediamine) to form AP-H, carboxylated and aminated enhanced aminophosphonate as AP-H, AP-COOH, and AP-NH were synthesized via a facile method. The structure of the synthesized sorbents was elucidated using different techniques; elemental analysis (CHNP/O), FT-IR, NMR (H-, C and P NMR), TGA and BET. The fabricated sorbents were exploited for Hg(II) removal from aqueous solution via sorption properties.

Tibiotalocalcaneal nailing for osteoporotic ankle fractures in the frail patient: a narrative review with a clinical score proposal for the decision-making process.

Osteoporotic ankle fractures result from mechanical forces that would not ordinarily result in fracture, known as 'low-energy' trauma, such as those equivalent to a fall from a standing height or less. Osteoporotic ankle fractures in frail patients are becoming more and more frequent in daily practice and represent a therapeutic challenge for orthopaedic surgeons. The main problems with frail patients are the poor condition of the soft tissues around the ankle, dependence for activities of daily living and high comorbidity.

Infected unstable Charcot ankle neuroarthropathy, any hope before amputation? A prospective study.

Background: Charcot neuroarthropathy is a destructive disease characterized by progressive bony fragmentation as a result of the isolated or accumulative trauma in patients with decreased sensation that manifests as dislocation, periarticular fractures, and instability. In this study, we present the results of salvage procedure of the ankle Charcot neuroarthropathy using aggressive debridement and Ilizarov frame fusion with early weight bearing.

Methods: Twenty-three patients with severely infected ulcerated and unstable Charcot neuroarthropathy of the ankle were treated between 2013 and 2018.

Management of Ankle Charcot Neuroarthropathy: A Systematic Review.

Background: Charcot neuroarthropathy is a non-infective, destructive process occurring in patients rendered insensate by peripheral neuropathy, which is caused mainly by diabetes. Repetitive trauma from standing and walking provides a neuro-traumatic stimulus that leads to dislocation, or peri-articular fracture, or both, within the ankle. This review concentrates on the management protocols regarding the ankle only.

Conservative Treatment of Ankle Osteoarthritis.

Despite the disabling nature of ankle osteoarthritis (OA), there is poor scientific evidence for a conservative treatment compared to the hip and knee OA. In this regard, most of the treatment options in use are not based on clinical studies of the ankle, and they are extracted from evidence obtained from clinical studies of other lower limb joints. However, this does not seem to be a good idea, since the aetiology of ankle OA is quite different from that of the hip or knee.

Analysis of the uninjured tibiofibular syndesmosis using conventional CT-imaging and axial force in different foot positions.

Background: Syndesmosis measurments and indices have been controversial and showed interindividual variability. The purpose of this study was to analyze, by conventional axial computed tomography images and a simulated load device, the uninjured tibiofibular syndesmosis under axial force and forced foot positions.

Methods: A total of 15 healthy patients (30 ankles) were studied using adjustable simulated load device (ASLD).

Functional results and quality of life after joint preserving or sacrificing surgery in Charcot-Marie-Tooth foot deformities.

Introduction: The purpose of this study was to assess the functional results, quality of life, and complications in two groups of Charcot-Marie-Tooth (CMT) patients according to the type of surgical operations, joint preserving, or joint sacrificing surgery.

Methods: Fifty-two feet in forty-six patients with CMT who had undergone surgical deformity correction were divided into two groups based on the main surgical procedure for the correction: Class I (joint preserving surgery) and class II (joint sacrificing surgery). Foot ankle disability index (FADI) and short form 12 version 2 (SFV were documented pre-operative and 12 months post-operative.

A new route for manufacturing poly(aminophosphonic)-functionalized poly(glycidyl methacrylate)-magnetic nanocomposite - Application to uranium sorption from ore leachate.

A high-energy ball milling of magnetite nanoparticles with amino-phosphonic functionalized poly(glycidyl methacrylate) polymer is used for manufacturing a highly efficient magnetic sorbent for U(VI) sorption from aqueous solutions. The Uranyl ions were adsorbed through the binding with amine and phosphonic groups as confirmed by Fourier Transform infrared (FTIR) and X-ray photoelectron spectroscopy (XPS) analyses. The maximum sorption capacity (up to 270 mg U g) occurred at pH = 3-4; Langmuir isotherm well describes the sorption process.

Facile synthesis of functionalized polyglycidyl methacrylate-magnetic nanocomposites for enhanced uranium sorption.

Designing and fabricating nanocomposite magnetic sorbents (with more accessible active sites for achieving high sorption capacities, selectivity and rapid kinetics) has become an impending challenge in the removal of radionuclides. Two core-shell multifunctional magnetic-nanocomposites have been prepared suitably to be used as sorbents using facile two-step processes. In the first step, after synthesis of parent PGMA microparticles (by a dispersion polymerization method), the grafting of aminoalkylcarboxylate and aminoalkylphosphonic ligands ( an intermediary amination step of PGMA) allows increasing sorption capacities due to the specific reactivity of carboxylate and phosphonate groups, giving iminodiacetate (IDA-PGMA) and iminodiphosphonate (IDP-PGMA), respectively.

Medial Ankle Instability: The Deltoid Dilemma.

Diagnosis and treatment of medial ankle instability (MAI) are still controversial and poorly discussed in literature. The purpose of this review is to highlight different clinical presentations of MAI and develop a guide for its management. The deltoid ligament complex is injured more commonly than expected, because deltoid ligament injuries may either be isolated or occur in combination with other lesions, such as lateral ankle ligament injury, posterior tibial tendon insufficiency, osteochondral lesion, and others.

Debridement and hinged motion distraction is superior to debridement alone in patients with ankle osteoarthritis: a prospective randomized controlled trial.

Purpose: To evaluate and compare complication rates and postoperative outcomes in patients with ankle debridement alone vs. debridement and hinged ankle distraction arthroplasty.

Methods: A total of 50 patients with posttraumatic ankle osteoarthritis (OA) with a mean age of 40.

Uranium and neodymium biosorption using novel chelating polysaccharide.

A direct reaction is described to prepare hydrophobic α-aminomethylphosphonic acid as a novel chitosan-based material. It exhibits chelating properties for polyvalent metal ions such as U(VI) and Nd(III) ions. The new sorbent was fully characterized using Elemental analysis, scanning electron microscope (SEM) and FTIR spectra.

Management of Nonunited Talar Fractures With Avascular Necrosis by Resection of Necrotic Bone, Bone Grafting, and Fusion With an Intramedullary Nail.

Background: The presence of nonunion of a talar fracture with displacement, together with complete avascular necrosis, is a challenging entity to treat.

Methods: Twelve patients, 8 men (66.7%) and 4 women (33.

How To Diagnose and Treat Infection in Total Ankle Arthroplasty.

Periprosthetic infection after total ankle arthroplasty (TAA) is a serious complication, often requiring revision surgery, including revision arthroplasty, conversion to ankle arthrodesis, or even amputation. Risk factors for periprosthetic ankle infection include prior surgery at the site of infection, low functional preoperative score, diabetes, and wound healing problems. The clinical presentation of patients with periprosthetic ankle joint infection can be variable and dependent on infection manifestation: acute versus chronic.