Modification of chitosan-ethyl formate polymer with zinc oxide nanoparticles and β-CD to minimize the harmful effects of Alternaria early blight on Vicia faba.

Derivatives of chitosan-ethyl formate polymers (Chs-EF) show promise as biologically relevant materials. The novelty of this study lies in the innovative use of Chs-EF doped with zinc oxide nanoparticles and beta-cyclodextrin, which significantly enhances the polymers' protective activities against Alternaria early blight disease in Vicia faba by improving both disease resistance and plant health. After doping Chs-EF with zinc oxide nanoparticles (ZnONPs) and inserting it into the beta-cyclodextrin (CD), two products emerged: Chs-EF/ZnONPs and Chs-EF/CD.

One-pot synthesis of novel chitosan-salicylaldehyde polymer composites for ammonia sensing.

Chitosan (Chs)-salicylaldehyde (Sal) polymer derivatives were formed via the reaction of Chs-Sal with zinc oxide nanoparticles (ZnO NPs) and beta-cyclodextrin (β-CD). These polymers were synthesized through inclusion with β-CD and doping with ZnO NPs to give pseudopolyrotaxane and Chs-Sal/ZnO NPs composite, respectively, for low-temperature detection and sensing of NH vapors as great significance in environmental control and human health. Additionally, the polymer (Chs-Sal/β-CD/ZnO NPs) was prepared via the insertion of generated composite (Chs-Sal/ZnO NPs) through β-cyclodextrin ring.

Self-perception of Voice Handicap in COVID 19 Patients.

Voice abnormalities were reported in patients during the course of COVID-19 infection. This study aims to evaluate the effect of COVID 19 infection on the self-perception of voice handicap in positive COVID 19 patients in addition to investigating the factors that might correlate with voice handicap if present. Voice handicap index-10 was filled in by 200 patients that were confirmed to be COVID 19 positive based on the RT-qPCR and symptomatology of the disease.

A comprehensive review on preparation, functionalization and recent applications of nanofiber membranes in wastewater treatment.

The direct discharge of significant amounts of polluted water into water bodies causes adverse ecological and human health effects. This severe deterioration in water quality creates significant challenges to meet the growing demand for clean water. Therefore, the world urgently needs environmentally friendly advanced technology to overcome this global crisis.

Nitro-Substituted Benzaldehydes in the Generation of Azomethine Ylides and Retro-1,3-Dipolar Cycloadditions.

1,3-Dipolar cycloaddition of 2- and 3-nitrobenzaldehydes with 2-aminomethylpyridine and ethyl (2)-2-cyano-3-(4-nitrophenyl)prop-2-enoate yielded -cycloadducts as the sole products under various reaction conditions. Fortuitously, 4-nitrobenzaldehyde behaved differently in three- and four-component cascades to produce a mixture of - and '-cycloadducts. This reaction is solvent- and temperature-dependent, and consequently, both the - and '-cycloadducts were synthesized in an excellent regio-, stereo-, and chemoselective fashion.