Heteroepitaxial growth of ZIF-67 nanoparticles on the ZIF-L(Zn) nanosheets for fabrication of Pebax mixed matrix membranes with highly efficient CO separation.

ZIF-67 nanoparticles were grown on ZIF-L(Zn) nanosheets by in-situ heteroepitaxial method, resulting in ZIF-67@ZIF-L(Zn) as a charming two-dimensional (2D) nanocomposite for incorporation into the Pebax-1657 and improving its CO/N separation performance. The fabricated nanofillers and membranes were analyzed by characterization tests (FTIR, XRD, FESEM, and EDAX-mapping) and gas separation experiments (effect of filler loading, filler type, feed pressure, and long-term stability). It was observed that the nanosheets were well dispersed in the matrix, and they had formed a proper interaction by creating hydrogen bonds at the interface; in addition, due to their crystalline nature, they increased the crystallinity of the MMMs.

A thermodynamic study on relationship between gas separation properties and microstructure of polyurethane membranes.

The lattice fluid (LF) thermodynamic model and extended Vrentas' free-volume (E-VSD) theory were coupled to study the gas separation properties of the linear thermoplastic polyurethane (TPU) membranes with different chemical structures by analyzing their microstructures. A set of characteristic parameters were extracted using the repeating unit of the TPU samples and led to prediction of reliable polymer densities (AARD < 6%) and gas solubilities. The viscoelastic parameters, which were obtained from the DMTA analysis, were also estimated the gas diffusion vs.

CO-selective poly (ether-block-amide)/polyethylene glycol composite blend membrane for CO separation from gas mixtures.

This work focuses on the preparation of composite blend membranes based on poly (ether-block-amide) (Pebax-1657) by incorporating polyethylene glycol (PEG) for gas separation applications. The influence of PEG with different molecular weights (PEG600, PEG1500, and PEG4000) at loading content in the range of 10%wt. to 40%wt.

The impact of carbon monoxide inhalation on developing noise-induced hearing loss in guinea pigs.

Carbon monoxide (CO) poisoning is one of the most common types of fatal poisonings worldwide. Acute exposure to high levels of CO as well as chronic exposure to low levels of CO and excessive noise can lead to high frequency hearing loss. In this study, twelve guinea pigs were randomly divided into two groups: (1) exposed to noise and (2) exposed to noise plus CO.

Surface modification of a PES membrane by corona air plasma-assisted grafting of HB-PEG for separation of oil-in-water emulsions.

The main goal of this study is to modify a polyethersulfone (PES) membrane by grafting with hyperbranched polyethylene glycol (HB-PEG) using corona air plasma to intensify the anti-fouling properties of the prepared membrane. The separation efficiency and fouling tendency of the modified membranes were evaluated for the treatment of a synthetic oily wastewater. A mechanism was proposed for the HB-PEG grafting on the surface of the corona treated PES membranes and all steps of the grafting were described in detail.

Superior performance of surface-treated NaX@Pebax-1657 membranes for O/N separation.

In this study, the performances of mixed matrix composite membranes (MMCMs) containing surface-treated NaX nanocrystals (ST-NaX-NCs) were experimentally and theoretically investigated for O/N separation. For this purpose, the MMCMs were fabricated by the casting solution method and characterized by various analyses. The results reveal that there is a robust interaction between the polymer chains and the ST-NaX-NCs, and that the ST-NaX fillers are uniformly dispersed in the polymer matrix.

Thermophysical and rheological properties of sorbitol + ([mmim](MeO)PO) ionic liquid solutions: Solubility, density and viscosity.

In this study, the solubility, density and viscosity of sorbitol as a sugar alcohol in the ([mmim](MeO)PO) ionic liquid (IL) were measured. The results indicated that sorbitol is highly soluble in this IL. The Flory-Huggins model with an average value for the χ parameter was successfully applied to predict the solubility of sorbitol in IL.

CO-philic moderate selective layer mixed matrix membranes containing surface functionalized NaX towards highly-efficient CO capture.

A functional moderate selective layer mixed matrix membrane (F-MSL-MMM) is a promising candidate to obtain superior separation of industrial gases, compared to commonly mixed matrix membranes. In this work, highly permeable and selective F-MSL-MMMs consisting of a moderate Pebax layer filled with functionalized NaX nano-zeolite over a microstructure PES support layer with the desired operating stability were prepared to investigate the effect of -COOH surface functionalization on the NaX nano-zeolites and to achieve the efficient separation of CO/N, CO/CH and CH/N gas mixtures. It was found that modification of the nano-zeolite had significant effects on the morphology and gas separation performance of the F-MSL-MMMs.

Solubility of fructose in water-ethanol and water-methanol mixtures by using H-bonding models.

The solubility of fructose in water-ethanol and water-methanol mixtures and the saturated density of each solution at 20, 30, and 40 °C over a range of water mass percentage have been measured. Also, a new modification of the Wilson model has been proposed to describe solubility data satisfactorily. The H-UNIQUAC and H-NRTL models were applied and a comparison between these 3 models was carried out.

Pervaporative removal of acrylonitrile from aqueous streams through polydimethylsiloxane membrane.

This study describes the successful separation of acrylonitrile (ACN) from dilute aqueous streams using pervaporation process. The influences of ACN feed concentration, permeate pressure, operating temperature, feed flow rate and membrane thickness on the membrane separation performance were investigated. The results showed that with an increase in ACN concentration in the feed solution, the permeation flux of ACN increased while the enrichment factor decreased.