Assessment of Supercritical CO Extraction as a Method for Plastic Waste Decontamination.

Due to the lack of advanced methods to clean plastic waste from organic contaminants, this study aimed at evaluating supercritical extraction as a decontamination method. Oil-adhesive high-density polyethylene (HD-PE) oil containers were subjected to supercritical extraction using supercritical carbon dioxide. The extraction was conducted at 300 bar, applying various temperatures (i.

Studying nanostructure gradients in injection-molded polypropylene/montmorillonite composites by microbeam small-angle x-ray scattering.

The core-shell structure in oriented cylindrical rods of polypropylene (PP) and nanoclay composites (NCs) from PP and montmorillonite (MMT) is studied by microbeam small-angle x-ray scattering (SAXS). The structure of neat PP is almost homogeneous across the rod showing regular semicrystalline stacks. In the NCs the discrete SAXS of arranged crystalline PP domains is limited to a skin zone of 300 m thickness.

Extruded blend films of poly(vinyl alcohol) and polyolefins: common and hard-elastic nanostructure evolution in the polyolefin during straining as monitored by SAXS.

Straining of PVA/PE and PVA/PP blends (70:30) is monitored by small-angle x-ray scattering (SAXS). Sheet-extruded films with different predraw ratio are investigated. The discrete SAXS of predrawn samples originates from polyolefin nanofibrils inside of polyolefin microfibrils immersed in a PVA matrix.