Spectrochim Acta A Mol Biomol Spectrosc
November 2024
This study employed advanced spectroscopic techniques to investigate the structural and optical properties of chitosan (CS) biopolymer films modified with natural dyes from Cosmos Sulphureus Cav. (CSC) flowers. FTIR results indicated that the inclusion of CSC dyes led to broader absorbance and decreased transmittance.
View Article and Find Full Text PDFThis review article covers the synthesis and design of conjugated polymers for carefully adjusting energy levels and energy band gap (EBG) to achieve the desired photovoltaic performance. The formation of bonds and the delocalization of electrons over conjugated chains are both explained by the molecular orbital theory (MOT). The intrinsic characteristics that classify conjugated polymers as semiconducting materials come from the EBG of organic molecules.
View Article and Find Full Text PDFIn this work, the green method was used to synthesize Sn-metal complex by polyphenols (PPHs) of black tea (BT). The formation of Sn-PPHs metal complex was confirmed through UV-Vis and FTIR methods. The FTIR method shows that BT contains NH and OH functional groups, conjugated double bonds, and PPHs which are important to create the Sn-metal complexes.
View Article and Find Full Text PDFIn this research, direct band gap polymer composites with amorphous phase, which are imperative for optoelectronic devices applications were synthesized. The solution cast technique was used to produce polyethylene oxide (PEO)/calcium titanate (CaTiO) nanocomposite (NC) films. The X-ray diffraction (XRD) confirms the growth of amorphous nature within PEO with CaTiO addition.
View Article and Find Full Text PDFIn this work, a green approach was implemented to prepare polymer composites using polyvinyl alcohol polymer and the extract of black tea leaves (polyphenols) in a complex form with Co ions. A range of techniques was used to characterize the Co complex and polymer composite, such as Ultraviolet-visible (UV-Visible) spectroscopy, Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD). The optical parameters of absorption edge, refractive index (), dielectric properties including real and imaginary parts (, and ) were also investigated.
View Article and Find Full Text PDFPolymers (Basel)
April 2021
The influence of dispersing Al-metal complex on the optical properties of PVA was investigated using UV-visible spectroscopy. Polymer composite films with various Al-complex amounts in the PVA matrix were arranged by solution casting technique by means of distilled water as a widespread solvent. The formation of Al-metal complex was verified through Ultraviolet-visible (UV-Vis) and Fourier-transform infrared spectroscopy (FTIR) examinations.
View Article and Find Full Text PDFIn the current study, polymer nanocomposites (NCPs) based on poly (vinyl alcohol) (PVA) with altered refractive index and absorption edge were synthesized by means of a solution cast technique. The characterization techniques of UV-Vis spectroscopy and XRD were used to inspect the structural and optical properties of the prepared films. The XRD patterns of the doped samples have shown clear amendments in the structural properties of the PVA host polymer.
View Article and Find Full Text PDFIn the current study, the film fabrication of polystyrene (PS) based polymer nanocomposites (NCs) with tuned refractive index and absorption edge was carried out using the solution cast method. X-ray diffraction (XRD) and ultraviolet-visible (UV-Vis) light characterization techniques were performed. The structural and optical properties of the prepared films were specified.
View Article and Find Full Text PDFPolymer electrolytes and composites have prevailed in the high performance and mobile marketplace during recent years. Polymer-based solid electrolytes possess the benefits of low flammability, excellent flexibility, good thermal stability, as well as higher safety. Several researchers have paid attention to the optical properties of polymer electrolytes and their composites.
View Article and Find Full Text PDFDye-doped polymer films of Poly(methyl methacrylate) PMMA have been prepared with the use of the conventional solution cast technique. Natural dye has been extracted from environmentally friendly material of green tea (GT) leaves. Obvious Fourier transform infrared (FTIR) spectra for the GT extract were observed, showing absorption bands at 3401 cm, 1628 cm, and 1029 cm, corresponding to O⁻H/N⁻H, C=O, and C⁻O groups, respectively.
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