Quickly UV-curing protective coating for cotton fabrics.

In order to eliminate the numerous limitations in application of cotton fibers, we designed and made a protective coating that changes many features of these material (such as water repellency or reducing the rate of thermal degradation), but does not change its natural flexibility and macroscopic appearance. The coating we developed consists a UV-crosslinked polysiloxanes together with organophosphates. The coating preparation process takes only a few minutes and takes place easily at room temperature.

Thiol-ene click reaction as an effective tool for the synthesis of PEG-functionalized alkoxysilanes-precursors of anti-fog coatings.

The article presents a very simple method of glass modification to obtain the anti-fog effect. Silanes containing two types of functional groups, namely a hydrophilic and polar polyether group and an alkoxysilyl group (to bond with the surface of the modified material) were synthesized in thiol-ene reactions. The hydrothiolation reactions of polyethers containing a C=C terminal bond with mercaptoalkoxysilane proceeded efficiently, yielding quantitatively appropriate products under mild reaction conditions.

Fluorocarbosilane-Based Protective Coatings for Concrete.

The effectiveness of protective coatings based on 3-(2,2,3,3,4,4,5,5-octafluoropentyloxy)propyltriethoxysilane (OFTES) in protecting concrete surfaces against water was tested. For the synthesis of OFTES, 2,2,3,3,4,4,5,5-octafluoropentanol, which is a by-product in the synthesis of poly(tetrafluoroethylene), was used. The proposed silane is a cheaper alternative to the fluorinated organosilicon compounds currently used.

Organosilicons of different molecular size and chemical structure as consolidants for waterlogged archaeological wood - a new reversible and retreatable method.

Ineffectiveness of the chemicals applied so far for waterlogged wood conservation created the need to develop new more, efficient and reliable agents. As an alternative, a new method with the use of organosilicon compounds differing in chemical composition and molecular weight has been investigated. The results obtained show the potential of organosilicons as consolidants in waterlogged wood conservation able to effectively stabilise wood dimensions upon drying.