A nanostructured device based on poly(vinyl alcohol) (PVA) loaded with a cross-linked chitosan (CH) emulsion, soy lecithin, and peppermint essential oil (Mentha piperita) was designed for topical applications using an electrospinning instrument coupled to a rotary drum collector. Different suspensions were obtained by varying the PVA to emulsion ratio (PVA:Em) 87.5:12.
View Article and Find Full Text PDFRecently, the development of materials with antimicrobial properties has become a challenge under scrutiny. The incorporation of copper nanoparticles (NpCu) into a chitosan matrix appears to represent a viable strategy to contain the particles and prevent their oxidation. Regarding the physical properties, the nanocomposite films (CHCu) showed a decrease in the elongation at break (5 %) and an increase in the tensile strength of 10 % concerning chitosan films (control).
View Article and Find Full Text PDFInt J Biol Macromol
February 2019
Chitosan-based nanocomposites have a significant industrial impact related to the possibility to design and create new materials and structures. Cellulose nanocrystals (CNC) can be extracted from microcrystalline cellulose (MCC) by controlled acid hydrolysis with HSO. This work was focused on: to study the microstructure of CNC isolated from MCC after different hydrolysis times; to develop nanocomposites chitosan-based films; to characterize their structural and thermo-mechanical properties; to analyze the spectral differences among samples by means of ATR-FTIR in combination with principal component analysis (PCA) and square partial minimums model (PLS).
View Article and Find Full Text PDFIndividual films of polyhydroxyalkanoates (PHA) and polylactic acid (PLA) and their blends were developed by solvent casting. PHA was obtained from activated sludges from a wastewater-treatment system at a laboratory scale. This work focused on analyzing the microstructural properties and thermal behaviors of individual films of PHA and PLA as well as those of their blends.
View Article and Find Full Text PDFThe goal of this work was to investigate the physicochemical properties of methylcellulose (MC) based films as stabilizers of two strains of lactobacilli: Lactobacillus delbrueckii subsp. bulgaricus CIDCA 333 and Lactobacillus plantarum CIDCA 83114. The incorporation of 3% w/v fructo-oligosaccharides (FOS) into the MC film formulation improved the viability of L.
View Article and Find Full Text PDFJ Agric Food Chem
January 2012
This work was focused on studying the changes undergone by heat-treated chitosan films with and without tannic acid addition by monitoring both microstructure and physical properties. Once the films were submitted to different heat treatments, they exhibited higher barrier properties as well as lower water uptake, solubility, and moisture content. These results were also confirmed through X-ray patterns, which changed from the hydrated to the anhydrous conformation, sharper FTIR peaks specifically associated with water, and shift of T(g) toward higher temperatures determined by DMA.
View Article and Find Full Text PDFBackground: As a result of consumers' health concerns and the trend towards healthier and low-fat food products, research has been undertaken to reduce the amount of fat absorbed in fried foods. This work focused on studying the efficacy of sorbitol and glycerol as plasticizers of methylcellulose coatings used to reduce oil uptake during the frying process of potato chips
Results: Changes in color, mechanical properties, water activity and lipid oxidation during storage were monitored. Also, an explanation regarding the different performances between both methylcellulose coatings with and without plasticizer was attained and techniques from the field of packaging films such as dynamic mechanical analyzer (DMA) and Fourier transform infrared spectroscopy were applied to analyze the behavior of coatings submitted to the frying operation.