Polyurethane Aerogels Based on Cyclodextrins: High-Capacity Desiccants Regenerated at Room Temperature by Reducing the Relative Humidity of the Environment.

Polyurethane aerogels were prepared from a rigid aromatic triisocyanate (tris(4-isocyanatophenyl)methane) and cage-shaped α- and β-cyclodextrins as rigid polyols. Gelation was carried out in DMF using dibutyltin dilaurate as catalyst. Wet-gels were dried to aerogels (abbreviated as α- or β-CDPU-) with supercritical fluid CO.

Selective CO Sequestration with Monolithic Bimodal Micro/Macroporous Carbon Aerogels Derived from Stepwise Pyrolytic Decomposition of Polyamide-Polyimide-Polyurea Random Copolymers.

Polymeric aerogels (PA-xx) were synthesized via room-temperature reaction of an aromatic triisocyanate (tris(4-isocyanatophenyl) methane) with pyromellitic acid. Using solid-state CPMAS C and N NMR, it was found that the skeletal framework of PA-xx was a statistical copolymer of polyamide, polyurea, polyimide, and of the primary condensation product of the two reactants, a carbamic-anhydride adduct. Stepwise pyrolytic decomposition of those components yielded carbon aerogels with both open and closed microporosity.