Bimetallic NiCr nanoparticles decorated on carbon nanofibers (NiCr@CNFs) were synthesized through electrospinning and investigated as catalysts for hydrogen generation from the dehydrogenation of sodium borohydride (SBH). Four distinct compositions were prepared, with chromium content in the catalysts ranging from 5 to 25 weight percentage (wt%). Comprehensive characterization confirmed the successful formation of bimetallic NiCr@CNFs.
View Article and Find Full Text PDFThis work addresses the scarcity of energy resources and environmental issues by concentrating on the synthesis of biodiesel by the transesterification of waste cooking oil with methanol. Marble sludge (MS), a novel heterogeneous catalyst, was used to speed up the rate of reaction. The catalyst's physical and chemical characteristics were thoroughly examined using a variety of methods, including X-ray diffraction, X-ray Fluorescence, SEM, particle size distribution, and BET analysis.
View Article and Find Full Text PDFThe generation of H via the catalytic hydrolysis of sodium borohydride (SBH) has promise as a practical and secure approach to produce H, a secure and environmentally friendly energy source for the foreseeable future. In this study, distinctive trimetallic NiCoPd nanoparticle-supported carbon nanofibers (NiCoPd tri-NPs@CNFs) is synthesized via sol-gel and electrospinning approaches. The fabricated trimetallic catalysts show an excellent catalytic performance for the generation of H from the hydrolysis of SBH.
View Article and Find Full Text PDFThe present study involves the synthesis of photocatalytic composite nanofibers (NFs) comprising ilmenite nickel titanite-supported carbon nanofibers (NiTiO/TiO@CNFs) using an electrospinning process. The photocatalytic composite NFs obtained were utilized in hydrogen (H) production from the photohydrolysis of ammonia borane (AB). The experimental findings show that the photocatalytic composite NFs with a loading of 25 mg had a good catalytic performance for H generation, producing the stoichiometric H in 11 min using 1 mmol AB under visible light at 25 °C and 1000 rpm.
View Article and Find Full Text PDFRapid urbanization has negative effects on ecology, economics, and public health, primarily due to unchecked population growth. Sustainable building materials and methods are needed to mitigate these issues and reduce energy use, waste production, and environmental damage. This study highlights the potential of agricultural waste as a sustainable source of construction materials and provides valuable insights into the performance and benefits of using fired clay bricks made from pomegranate peel waste.
View Article and Find Full Text PDFThis study explores the potential for making lightweight bricks via the use of dry, pulverized spent mushroom materials (SMM) as a thermal insulator. There are five distinct replacement proportions of SMM that are used, and they range from 0% to 15% of the weight of the clay. The firing of the fabricated bricks at temperatures of 700, 800, and 900 °C led to the development of pores on the interior surface of the bricks as a consequence of the decomposition of SMM.
View Article and Find Full Text PDFImplementing unified municipal solid waste management (MSWM) is often difficult due to socio-economic variables. However, spatial GIS models and statistical analysis of solid waste characterized by the weekdays, weekends, and festivals can somewhat mitigate the variance and assist with selecting suitable waste management methods. This paper presents the example of Rajouri, India, to propose a suitable MSWM based on Inverse Distance Weighted (IDW) intensity maps and statistical findings.
View Article and Find Full Text PDFExcessive urban construction is primarily driven by uncontrolled population growth, which has serious consequences for the environment, energy, cost, and human life in general when building materials are massively used. In terms of energy and economic efficiency, buildings that make use of sustainable construction materials and technologies perform better. This is because building in an eco-friendly way results in less waste.
View Article and Find Full Text PDFSodium borohydride (SBH) hydrolysis in the presence of cheap and efficient catalysts has been proposed as a safe and efficient method for generating clean hydrogen energy for use in portable applications. In this work, we synthesized bimetallic NiPd nanoparticles (NPs) supported on poly(vinylidene fluoride-co-hexafluoropropylene) nanofibers (PVDF-HFP NFs) via the electrospinning approach and reported an in-situ reduction procedure of the NPs being prepared by alloying Ni and Pd with varying Pd percentages. The physicochemical characterization provided evidence for the development of a NiPd@PVDF-HFP NFs membrane.
View Article and Find Full Text PDFThe successful support of bimetallic NiCo alloy nanoparticles (NPs) on poly(vinylidene fluoride-co-hexafluoropropylene) nanofibers (PVDF-HFP NFs) was achieved through electrospinning (ES) and in situ reduction. The synthesis and physicochemical characterization of Ni-Co@PVDF-HFP NFs with a range of bimetallic compositions (NiCo, x = 0, 0.1, 0.
View Article and Find Full Text PDFMetallic Co NPs@poly(vinylidene fluoride-co- hexafluoropropylene) nanofibers (PVFH NFs) were successfully synthesized with the help of electrospinning and in situ reduction of Co ions onto the surface of PVFH membrane. Synthesis of PVFH NFs containing 10, 20, 30, and 40 wt% of cobalt acetate tetrahydrate was achieved. Physiochemical techniques were used to confirm the formation of metallic Co@PVFH NFs.
View Article and Find Full Text PDFPolymers (Basel)
January 2023
Non-noble CuNi (x = 0, 0.1, 0,2, 0.3, 0.
View Article and Find Full Text PDFThe contamination of water due to present of dyes, poses serious health problems. Therefore, treatment of contaminated water is necessary to resolve this problem. A tailored co-precipitation technique has been successfully used to prepare FeO-multiwalled Carbon Nanotubes (MWCNTs)-Bentonite nanocomposite.
View Article and Find Full Text PDFSimple and inexpensive electrospinning and hydrothermal techniques were used to synthesize titania nanofibers (TiO NFs) (composite NFs) decorated with copper nanoparticle (Cu NPs). The fabricated composite NFs have been tested as a photocatalytic material to degrade methylene blue (MB) as a model dye under visible light. The introduced composite NFs have shown good photocatalytic activity compared with pristine TiO NFs; 100% and 50% of dye were degraded in 120 min for composite NFs and pristine TiO NFs, respectively.
View Article and Find Full Text PDFScientific advancements from 2002 to 2020 for coronaviruses, i.e., SARS-CoV and MERS-CoV outbreaks, could lead towards a better understanding of the exposure to a health crisis.
View Article and Find Full Text PDFIn the last three decades, pharmaceutical research has increased tremendously to offer safe and healthy life. However, the high consumption of these harmful drugs has risen devastating impact on ecosystems. Therefore, it is worldwide paramount concern to effectively clean pharmaceuticals contaminated water streams to ensure safer environment and healthier life.
View Article and Find Full Text PDFHydrogen (H) is a promising renewable energy source that can replace fossil fuels since it can solve several environmental and economic issues. However, the widespread usage of H is constrained by its storage and safety issues. Many researchers consider solid materials with an excellent capacity for H storage and generation as the solution for most H-related issues.
View Article and Find Full Text PDFMolecular scale modifications were achieved by spontaneous polarization which is favored in enhancements of β-crystallization phase inside polyvinylidene fluoride (PVDF) nanofibers (NFs). These improvements were much more effective in nano and submicron fibers compared to fibers with relatively larger diameters. Metallic nanoparticles (NPs) supported by nanofibrous membranes opened new vistas in filtration, catalysis, and serving as most reliable resources in numerous other industrial applications.
View Article and Find Full Text PDFElectrospun polyvinylidene fluoride (PVDF) fiber mats with average fiber diameters (≈200 nm, ≈2000 nm) were fabricated by controlled electrospinning conditions. These fiber mats were polarized using a custom-made device to enhance the formation of the electret β-phase ferroelectric property of the fibers by simultaneous uniaxial stretching of the fiber mat and heating the mat to the Curie temperature of the PVDF polymer in a strong electric field of 2.5 kV/cm.
View Article and Find Full Text PDFAllergic conjunctival disease (ACD) is a type of ocular allergy, which includes seasonal allergic conjunctivitis (SAC), perennial allergic conjunctivitis (PAC), and vernal keratoconjunctivitis (VKC). Little is known about the pattern of sensitization or prevalent aeroallergens among patients with isolated ACD in Egypt We aimed to evaluate the prevalence of skin prick test positivity to common aeroallergens among Egyptian patients with isolated allergic conjunctival disease. The study included 75 patients with isolated ACD recruited from a tertiary Egyptian outpatient clinic.
View Article and Find Full Text PDFBackground: Chelating therapy in transfusion-dependent patients with β-thalassemia major (β-TM) is mandatory to reduce the toxic effect of iron on the myocardium.
Aim: To evaluate the impact of low and high dose of oral chelating therapy (deferasirox) on pulsed and tissue echocardiographic indices in patients with β-TM.
Methods: This interventional study conducted on patients with transfusion-dependent β-TM (n=38) on deferasirox 20 mg/kg/d medication, group (DFX-20) for at least 6 months, followed by administration of a higher dose of deferasirox, 40 mg/kg/d, group (DFX-40) for another 6 months.
Background: Doppler echocardiographic studies of the left ventricle (LV) function in patients with β-Thalassemia Major (β-TM) had shown different patterns of systolic and diastolic dysfunctions associated with abnormal serum brain natriuretic peptide (BNP).
Aim: This cross-sectional study was designed to study the LV systolic and diastolic functions and correlate that with serum level of N-terminal pro brain natriuretic hormone (NT- pro BNP) in patients with β-TM using Pulsed Doppler (PD) and Tissue Doppler (TD) echocardiography.
Methods: The study was conducted on patients with β-TM (n = 38, age 15.
Background: Hypertensive crisis (HC) is a common medical emergency associated with acute rise in arterial blood pressure that leads to end-organ damage (EOD). Therefore, it is imperative to find markers that may help in the prediction of EOD in acute hypertensive crisis.
Aim: To assess the clinical presentations on admission; echocardiographic changes of pulsed and tissue Doppler changes in EOD patients compared with no EOD; and the risk of developing end organ damage for clinical and biochemical variables in hypertension crisis.
Background: The prevalence and epidemiological data of atrial fibrillation (AF) among multi-ethnic populations is less well studied worldwide.
Aim: Evaluation of the prevalence and predisposing factors of AF in patients who were admitted to acute medical emergencies (ER) in Bahrain over the period of one year.
Methods: Two hundred and fifty three patients with onset of AF were studied.