Superhydrophobic Polyaniline-Siloxane Coatings with Excellent Barrier and Active Corrosion Protection Properties for Mild Steel.

Although superhydrophobic surfaces have attracted much attention in research, their high cost, poor durability, and challenging manufacturing processes have prevented their widespread application. Here, we describe a simple method of preparing superhydrophobic polyaniline (PANI) pigments and their application in protective coatings. Doping polyaniline pigments with low surface energy perfluorodecanoic acid (PFDA) allowed them to overcome their intrinsic high surface energy, and the resultant PANI-PFDA pigments showed superhydrophobicity.