Study of physical properties of a ferrimagnetic spinel CuMnO: spin dynamics, magnetocaloric effect and critical behavior.

The present work reports a detailed study of the spin dynamics, magnetocaloric effect and critical behaviour near the magnetic phase transition temperature, of a ferrimagnetic spinel CuMnO. The dynamic magnetic properties investigated using frequency-dependent ac magnetic susceptibility fitted using different phenomenological models such as Neel-Arrhenius, Vogel-Fulcher and power law, strongly indicate the presence of a cluster-glass-like behavior of CuMnO at 40 K. The magnetization data have revealed that our compound displays an occurrence of second-order paramagnetic (PM) to ferrimagnetic (FIM) phase transition at the Curie temperature = 80 K as the temperature decrease.

Structural, optical and dielectric properties of CuMnO spinel nanoparticles.

In this study, a CuMnO spinel was successfully synthesized by a sol-gel method at 500 °C for 5 h and characterized by different techniques. X-ray diffraction (XRD), Fourier transformation infrared (FTIR) spectroscopy and Raman spectroscopic analyses confirmed the formation of a spinel cubic structure with the 3̄ space group. The SEM proves that the grain size of our compound is of the order of 48 nm.