The germanate CsSbGeO, grown spontaneously via the high-temperature solution method from CsMoO used as a flux, crystallizes in the orthorhombic system with = 12.3636(2), = 13.8521(2), = 31.
View Article and Find Full Text PDFWe report for the first time the full crystal structure, the electronic structure, the lattice dynamics, and the elastic constants of metastable monoclinic AlGe. In addition to ultrarapid cooling techniques such as melt spinning, we show the possibility of obtaining monoclinic AlGe by water-quenching in a quartz tube. Monoclinic AlGe and rhombohedral AlGe are competing phases with similar stability since they both begin to decompose above 230 °C.
View Article and Find Full Text PDFThe dissolution of α-FePO(4) and the α-Ga(0.75)Fe(0.25)PO(4) solid solution with α-quartz-type structures under hydrothermal conditions in 1 M HNO(3) aqueous solution was investigated by in situ X-ray absorption spectroscopy (XAS) at the Fe K-edge.
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