Pollution by heavy metals is a major global issue. The biosorptive removal of Cd and Cu by () was evaluated in this work. FTIR and XRD analysis were performed to determine the characteristics of the biosorbent.
View Article and Find Full Text PDFIn this paper, for the first time, we report the use of a new carbon paste electrode based on a low-cost pencil graphite powder modified with polyaniline (PANI) and green synthesized copper oxide nanoparticles using extract as a sensor for Cd, Pb, and Hg. The elaborated electrode was characterized by FT-IR spectroscopy, field-emission gun scanning electron microscopy (FEG-SEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), and simultaneous thermal analysis (TGA/DSC). The electrochemical behavior of the sensor was evaluated using cyclic voltammetry (CV) and electrochemical impedance spectroscopy techniques.
View Article and Find Full Text PDFDuring the recent decades, adverse effects of unexpected contaminants, such as heavy metals on raw cow milk quality, have threatened human health. The objective of this study was to determine heavy metal levels in raw milk collected from autochthonous bovine breeds in the eastern region of Algeria. Eighty-eight pooled milk samples were analyzed using atomic absorption spectrometry for Pb, Cd, Cr, Cu, Ni, Fe, and Zn, and dietary risks were estimated for infants, children, and adults with minimum, average, and maximum milk consumption scenarios.
View Article and Find Full Text PDFA three dimensional (3D) non-enzymatic glucose disposable electrochemical sensor based on screen-printed graphite macroelectrodes (SPEs), modified with nickel hydroxide (Ni(OH)/SPE), copper hydroxide (Cu(OH)/SPE) and mixed (Ni(OH)/Cu(OH)/SPE) microstructures were prepared by a facile and cost-effective electrochemical method for the first time. Their morphologies and structures were analyzed by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX) and X-ray diffraction (XRD). The electrochemical performances of the modified SPEs were evaluated by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and amperometric measurements.
View Article and Find Full Text PDFSurface morphology modification of the Nafion 117 membrane has been investigated by atomic force microscopy. The effects of water and methanol on the topography and structure of the surface were studied using the contact and tapping atomic force microscopy modes. Nafion topography considerably changes when samples absorb water.
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