On the Transient Decomposition and Reaction Kinetics of Zinc Dialkyldithiophosphate.

Despite the ubiquitous use of the zinc dialkyldithiophosphate (ZDDP) as an antiwear additive, no complete information is yet available on its exact decomposition reactions and kinetics to form triboreactive protective films on contacting surfaces. This hinders the replacement of ZDDP with more environmentally friendly additives of similar antiwear capabilities. Using a multitechnique approach, this study shows that before the formation of a phosphate-rich protective film, the decomposition of ZDDP proceeds by forming intermediate zinc sulfide and sulfate species, which can be mechanically mixed with the iron oxides on the rubbing steel surfaces.