Revealing the Catalytic Activities of Single-Dispersed Pd Clusters Embedded on Hollow Nanoparticles toward the Hydrogen Evolution Reaction.

Hydrogen evolution reaction (HER) is one of the revolutionary aspects that grab lots of attention for the production of clean energy sources, increasing the demands of revealing the intrinsic activities of HER catalysts for designing efficient candidates. Based on using only surface active sites on solid nanoparticles (SNPs), catalysts with high atom dispersion are immensely desirable to magnify their efficiency through maximum atom utilization. Herein, we employed hollow mesoporous silica nanoparticles (HMSNPs) as an insulating nanoplatform for engineering single-dispersed Pd clusters on their surface, assuring high dispersion of the Pd clusters.