Brain functional alteration and cognitive performance in cardiovascular diseases: a systematic review of fMRI studies.

Background: Functional magnetic resonance imaging (fMRI) is a useful tool to evaluate brain inefficiencies secondary to cardiovascular diseases (CVDs); nevertheless, limited fMRI studies have been conducted to investigate the effect of CVDs on brain functional changes and cognitive function. This systematic review aims to explore, synthesise, and report fMRI outcomes (resting state and task-based) and cognitive performance in patients with CVDs.

Methods: Two reviewers independently searched published literature until April 2024 on ScienceDirect, PubMed, Web of Science, and ClinicalTrials.

Optimization of extraction for efficient recovery of kenaf seed protein isolates: evaluation of physicochemical and techno-functional characteristics.

Background: Kenaf seeds are a rich source of protein; however, finding the best extraction method is crucial to obtaining high-quality protein from these underutilized seeds. This research devised an optimized extraction process for best recovery of kenaf seeds protein using response surface methodology. The key parameters affecting the yield and protein content were optimized, including extraction pH (2-11), seed:water ratio (5:1-50:1), temperature (30-90 °C), and duration (20-360 min).

Bi-functional NiFeO/SrTiO S-scheme heterojunction for eminent performance photocatalytic treatment of sewage effluent and electrochemical hydrazine determination.

Devising of materials that afforded dual applicability in decontamination and pollutant detection were still a towering challenge owing to the increasing flux of discharge toxic contaminants over the years. Herein, the NiFeO nanoparticles-loaded on cube-like SrTiO (NiFeO/SrTiO) composite was fabricated by a two-step hydrothermal approach providing remarkable photocatalytic treatment and electrochemical sensing of noxious pollutants in wastewater. The material traits of the fabricated composite were scrutinized by myriad characterization approaches.

Relationship between carotid intima-media thickness and white matter hyperintensities in non-stroke adults: a systematic review.

Introduction: Literature suggests a common pathophysiological ground between carotid atherosclerosis (CAS) and white matter alterations in the brain. However, the association between carotid intima-media thickness (CIMT) and white matter hyperintensities (WMH) has not been conclusively reported. The current systematic review explores and reports the relationship between CIMT and WMH among asymptomatic/non-stroke adults.

Systematic review of cardiovascular magnetic resonance imaging T1 and T2 mapping in patients with Takotsubo syndrome.

Background: Current imaging advancements quantify the use of cardiovascular magnetic resonance (CMR) derived T1 and T2 tissue characterization as robust indicators for cardiomyopathies, but limited literature exists on its clinical application in Takotsubo syndrome (TTS). This systematic review evaluated the T1 and T2 parametric mapping to delineate the current diagnostic and prognostic CMR imaging outcomes in TTS.

Methods: A comprehensive literature search until October 2023 was performed on ScienceDirect, PubMed, Web of Science, and Cochrane Library by two independent reviewers adhering to the PRISMA framework.

Synergistic effect of dual phase cocatalysts: MoC-MoC quantum dots anchored on g-CN for high-stability photocatalytic hydrogen evolution.

The extensive examination of hexagonal molybdenum carbide (β-MoC) as a non-noble cocatalyst in the realm of photocatalytic H evolution is predominantly motivated by its exceptional capacity to adsorb H ions akin to Pt and its advantageous conductivity characteristics. However, the H evolution rate of photocatalysts modified with β-MoC is limited as a result of their comparatively low ability to release H through desorption. Therefore, a facile method was employed to synthesize carbon intercalated dual phase molybdenum carbide (MC@C) quantum dots (ca.

A Systematic Review and Meta-Analysis of Mapping Biopsy for Primary Extramammary Paget's Disease in Reducing Recurrence Following Surgical Excision.

Objective: To examine the association between the performance of mapping biopsies and surgical outcomes postexcision of extramammary Paget's disease (EMPD).

Background: Primary EMPD is a rare entity associated with poorly defined surgical margins and difficult-to-access sites of lesions. Surgical resection with clear margins remains the preferred management method.

Self-activated superhydrophilic green ZnInS realizing solar-driven overall water splitting: close-to-unity stability for a full daytime.

Engineering an efficient semiconductor to sustainably produce green hydrogen via solar-driven water splitting is one of the cutting-edge strategies for carbon-neutral energy ecosystem. Herein, a superhydrophilic green hollow ZnInS (gZIS) was fabricated to realize unassisted photocatalytic overall water splitting. The hollow hierarchical framework benefits exposure of intrinsically active facets and activates inert basal planes.

Retrospective insights into recent MXene-based catalysts for CO electro/photoreduction: how far have we gone?

The electro/photocatalytic CO reduction reaction (CORR) is a long-term avenue toward synthesizing renewable fuels and value-added chemicals, as well as addressing the global energy crisis and environmental challenges. As a result, current research studies have focused on investigating new materials and implementing numerous fabrication approaches to increase the catalytic performances of electro/photocatalysts toward the CORR. MXenes, also known as 2D transition metal carbides, nitrides, and carbonitrides, are intriguing materials with outstanding traits.

Recent Advances in Defect-Engineered Transition Metal Dichalcogenides for Enhanced Electrocatalytic Hydrogen Evolution: Perfecting Imperfections.

Switching to renewable, carbon-neutral sources of energy is urgent and critical for climate change mitigation. Despite how hydrogen production by electrolyzing water can enable renewable energy storage, current technologies unfortunately require rare and expensive platinum group metal electrocatalysts, which limit their economic viability. Transition metal dichalcogenides (TMDs) are low-cost, earth-abundant materials that possess the potential to replace platinum as the hydrogen evolution catalyst for water electrolysis, but so far, pristine TMDs are plagued by poor catalytic performances.

Modulating the Morphological Features of Hydrothermally Derived Nickel Cobaltite for Supercapacitor Application: Role of Precursor Anions.

Morphologically engineered porous electrodes show great promise in energy applications as they exhibit improved electrochemical activity owing to increased electrical conductivity, increased surface area, and a shorter path length for ion transport. Herein, the role of precursors (chlorides, acetates and nitrates) on the crystallinity and textural features of Nickel Cobaltite, obtained by the controlled precipitation through hydrothermal synthesis, is studied. The synthesis yielded urchin like structures with morphological variations in substructures based on the precursor anion types.

A Novel Nanocomposite Based on Triazine Based Covalent Organic Polymer Blended with Porous g-CN for Photo Catalytic Dye Degradation of Rose Bengal and Fast Green.

Metal free visible light active photocatalysts of covalent organic polymers (COPs) and polymeric graphitic carbon nitride (g-CN) are interesting porous catalysts that have enormous potential for application in organic pollutant degradation. Imine condensation for COPs, and thermal condensation for g-CN were used to produce the catalysts. FT-IR, Raman, NMR, UV-Vis Spectroscopy, X-ray diffraction, and scanning electron microscopy studies were used to investigate the structural, optical, and morphological features of the metal free catalysts.

Development of microwave-assisted nitrogen-modified activated carbon for efficient biogas desulfurization: a practical approach.

Removal of HS (hydrogen sulfide) from biogas is anticipated for higher energy conversion of methane (CH), while reducing the detrimental impacts of corroding the metal parts in the plant and its hazardous effect on humans and the environment. The introduction of microwave (MW) heating and nitrogen-modification could generate superior adsorbent features, contributing to high HS removal. Up to date, there is no work reported on the influence of physicochemical characteristics of nitrogen-modified carbon synthesized via MW and conventional heating (TH) methods and their performance in HS removal.

Enhanced synchronous photocatalytic 4-chlorophenol degradation and Cr(VI) reduction by novel magnetic separable visible-light-driven Z-scheme CoFeO/P-doped BiOBr heterojunction nanocomposites.

The co-existence of organic contaminants and heavy metals including 4-chlorophenol (4-CP) and Cr(VI) in aquatic system have become a challenging task in the wastewater treatment. Herein, the synchronous photocatalytic decomposition of 4-CP and Cr(VI) over new Z-scheme CoFeO/P-BiOBr heterojunction nanocomposites were revealed. In this work, the nanocomposites were successfully developed via a surfactant-free hydrothermal method.

Uncovering the multifaceted roles of nitrogen defects in graphitic carbon nitride for selective photocatalytic carbon dioxide reduction: a density functional theory study.

Surface defect engineering on the nanoscale has attracted extensive research attention lately; however, its role in modulating the properties and catalytic performance of a semiconducting material has not been comprehensively covered. Here, we systematically unraveled the effect of defect engineering towards textural, electronic and optical properties of graphitic carbon nitride (g-CN), as well as its photocatalytic mechanism of CO reduction using first-principle calculations by density functional theory through the introduction of various defect sites. Among the five unique atoms in g-CN, the vacancy site was found to be the most feasible at the two-coordinated nitrogen, N2.

A systematic review of the utilization of waste materials as aggregate replacement in stone matrix asphalt mixes.

The daily utilization of a large amount of raw materials is causing a rapid depletion of natural resources. The growth of the human population is accompanied by higher activities in the agricultural and manufacturing sectors that resulted in a larger volume of waste materials being disposed of in landfills each year. Researchers are seeking ways to reduce the adverse impact of waste materials on the environment.

Red Phosphorus: An Up-and-Coming Photocatalyst on the Horizon for Sustainable Energy Development and Environmental Remediation.

Photocatalysis is a perennial solution that promises to resolve deep-rooted challenges related to environmental pollution and energy deficit through harvesting the inexhaustible and renewable solar energy. To date, a cornucopia of photocatalytic materials has been investigated with the research wave presently steered by the development of novel, affordable, and effective metal-free semiconductors with fascinating physicochemical and semiconducting characteristics. Coincidentally, the recently emerged red phosphorus (RP) semiconductor finds itself fitting perfectly into this category ascribed to its earth abundant, low-cost, and metal-free nature.

A review on dry-based and wet-based catalytic sulphur dioxide (SO) reduction technologies.

While sulphur dioxide (SO) is known for its toxicity, numerous effective countermeasures were innovated to alleviate its hazards towards the environment. In particular, catalytic reduction is favoured for its potential in converting SO into harmless, yet marketable product, such as elemental sulphur. Therefore, current review summarises the critical findings in catalytic SO reduction, emphasising on both dry- and wet-based technology.

Ameliorating Cu reduction in microbial fuel cell with Z-scheme BiFeO decorated on flower-like ZnO composite photocathode.

BiFeO nanoparticle decorated on flower-like ZnO (BiFeO/ZnO) was fabricated through a facile hydrothermal-reflux combined method. This material was utilized as a composite photocathode for the first time in microbial fuel cell (MFC) to reduce the copper ion (Cu) and power generation concomitantly. The resultant BiFeO/ZnO-based MFC displayed distinct photoelectrocatalytic activities when different weight percentages (wt%) BiFeO were used.

Physical and Chemical Activation of Graphene-Derived Porous Nanomaterials for Post-Combustion Carbon Dioxide Capture.

Activation is commonly used to improve the surface and porosity of different kinds of carbon nanomaterials: activated carbon, carbon nanotubes, graphene, and carbon black. In this study, both physical and chemical activations are applied to graphene oxide by using CO and KOH-based approaches, respectively. The structural and the chemical properties of the prepared activated graphene are deeply characterized by means of scanning electron microscopy, Raman spectroscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectrometry and nitrogen adsorption.

Point-Defect Engineering: Leveraging Imperfections in Graphitic Carbon Nitride (g-C N ) Photocatalysts toward Artificial Photosynthesis.

Graphitic carbon nitride (g-C N ) is a kind of ideal metal-free photocatalysts for artificial photosynthesis. At present, pristine g-C N suffers from small specific surface area, poor light absorption at longer wavelengths, low charge migration rate, and a high recombination rate of photogenerated electron-hole pairs, which significantly limit its performance. Among a myriad of modification strategies, point-defect engineering, namely tunable vacancies and dopant introduction, is capable of harnessing the superb structural, textural, optical, and electronic properties of g-C N to acquire an ameliorated photocatalytic activity.

Plasma Concentrations of Pro-inflammatory Cytokine IL-6 and Antiinflammatory Cytokine IL-10 in Short- and Long-term Opioid Users with Noncancer Pain.

Introduction: Little is known whether the duration of opioid use influences the concentrations of pro- and anti-inflammatory cytokines.

Objectives: This study examined the plasma concentration of pro-inflammatory cytokine, interleukin 6 (IL-6), and anti-inflammatory cytokine, interleukin 10 (IL-10), in short-, and long-term opioid users with noncancer pain.

Materials And Methods: Adult patients with opioid therapy for noncancer pain were recruited from pain clinics at two tertiary hospital settings in Malaysia between February 2016 and March 2017.

An investigation on the relationship between physicochemical characteristics of alumina-supported cobalt catalyst and its performance in dry reforming of methane.

This study deals with the development of alumina-supported cobalt (Co/AlO) catalysts with remarkable performance in dry reforming of methane (DRM) and least carbon deposition. The influence of Co content, calcination, and reduction temperatures on the physicochemical attributes and catalyst activity of the developed catalysts was extensively studied. For this purpose, several characterization techniques including ICP-MS, H pulse chemisorption, HRTEM, H-TPR, N adsorption desorption, and TGA were implemented, and the properties of the developed catalysts were carefully analyzed.