Polylactic acid (PLA) can serve as a biodegradable alternative to traditional petroleum-based plastics, but its poor impact resistance and high production costs limit its applications. In this study, different contents of epoxidized epoxy soybean oil (ESO) were added as plasticizer to melt blend with polylactic acid (PLA), polypropylene (PP) and cotton stalk fiber (CSF), examining its impact on the mechanical properties, thermal stability, microstructure, and crystallization behavior of the blends. The results indicated that ESO reacted with PLA and CSF to form branched polymers and microgels.
View Article and Find Full Text PDFTo improve the efficiency of the methanol oxidation reaction (MOR) in direct methanol fuel cells (DMFCs), it is essential to develop catalysts with high catalytic activity. However, constructing polyatomic doped carbon nanomaterials and understanding the interaction mechanisms between dopant elements remain significant challenges. In this study, we propose nitrogen-doped carbon nanobox (CNB) derived from Zeolitic Imidazolate Framework-67 (ZIF-67) crystals as precursors to serve as carriers for highly efficient platinum nanoparticles (Pt NPs).
View Article and Find Full Text PDFDifferent chemical treatment methods were employed to modify the surface of cotton stalk fibers, which were then utilized as fillers in composite materials. These treated fibers were incorporated into polylactic acid/polypropylene melt blends using the melt blending technique. Results indicated that increasing the surface roughness of cotton stalk fibers could enhance the overall mechanical properties of the composite materials, albeit potentially leading to poor fiber-matrix compatibility.
View Article and Find Full Text PDFThe treatment of waste plastics has gradually become a hot topic in the current scientific community. In response to the needs for high-impact performance R-PP-based composites, carbon fiber (CF)-reinforced polyolefin elastomer (POE)/recycled polypropylene (R-PP) composite (CF/POE/R-PP) was prepared by the mechanical blending method, and its mechanical and thermal properties were systematically studied. It was found that the CF could effectively improve the bending and notch impact strength as well as enhance the thermal stability of POE/R-PP.
View Article and Find Full Text PDFPoly (3,4-ethylenedioxythiophene) (PEDOT)-based molecularly imprinted electrochemical sensors have attracted widespread attention for monitoring contaminants in food and the environment. However, there are still problems such as poor hydrophilicity, easy agglomeration, and low selectivity in its preparation. In this work, a novel molecularly imprinted composite hollow sphere was prepared by a molecular imprinting technique using nitrogen-doped hollow carbon spheres as matrix material, and PEDOT and poly(methacrylic acid) as monomers.
View Article and Find Full Text PDFDirect methanol fuel cells (DMFCs) are thought of as portable, sustainable, and non-polluting energy devices. The exploration of efficient and affordable catalysts for the methanol oxidation reaction (MOR) is significant for the industrial application of DMFCs. In this study, nitrogen-doped hollow carbon spheres (HCS) derived from polydopamine were proposed for the catalyst support for platinum nanoparticles (Pt NPs) for serving as the anode catalyst for DMFCs, and a composite support material was fabricated by in-situ oxidation of 3,4-ethylenedioxythiophene (ProDOT) with HCS to get core-shell structured poly(3,4-propylenedioxythiophene) (PProDOT)-embellished hollow carbon spheres (HCS) (PProDOT/HCS) for further improving the catalytic activity for supported catalyst.
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