Heliyon
July 2024
A catalyst from the pharmaceutical waste of calcium and magnesium tablets was synthesized for biodiesel production from waste Pistacia-Terebinthus (PT) oil with the aim of creating added value and presenting a new approach for the management of such wastes. For this purpose, magnesium and calcium tablet wastes with a mass ratio of 70:30 (wt%) were calcined. The catalyst was investigated by several methods, such as thermal gravimetric analysis, X-ray diffraction, Fourier transform infrared spectroscopy, field emission scanning electron microscopy, Brunauer-Emmett-Teller analysis, X-ray photoelectron spectroscopy, and CHNS/O elemental analysis.
View Article and Find Full Text PDFEstuaries play a crucial role in preventing the influx of metals from rivers into seas, thereby offering potential insights for the water purification industry. This study seeks to identify the key parameters (including pH, electricity conductivity (EC), and Eh) influencing the removal efficiency of Mn, Zn, Cu, Co, and Ni during natural and electro-flocculation processes in the Siahroud River estuary. The experiments were conducted in three stages, each representing varying salinity levels and voltage conditions, to determine the most effective parameters for metal removal.
View Article and Find Full Text PDFMetal contamination is one of the worldwide environmental issues. The main aim of this study was to evaluate the concentration, probable environmental risk, and source of investigated elements (Al, As, Co, Cr, Cu, Fe, Mn, Ni, and Zn) in sediments and water of the Gomishan wetland. Sediment contamination indices revealed sediments were solely polluted by As.
View Article and Find Full Text PDFThis study presents the development of a new sediment individual risk index (SIRI) and sediment complex risk index (SCRI) to assess heavy metal pollution in Anzali Wetland sediments. SIRI incorporates total metal concentrations, bioavailability, and sediment quality guidelines. SCRI, derived through principal component analysis (PCA), integrates SIRI for a comprehensive risk assessment.
View Article and Find Full Text PDFIn this study, the pollution and bioavailability of heavy metals in the sediments of Anzali Wetland were measured by analyzing data from sequential chemical extraction of sediments, risk assessment code (RAC), and sediment pollution indices. The average RAC results indicated that the risk from Zn, Cr, Cu, and Hg was low, while the risk from Pb, Ni, As, and Cd was moderate. To identify the sources of heavy metal pollution in the sediments of Anzali Wetland, multivariate statistical techniques such as Pearson correlation analysis, cluster analysis (CA), and principal component analysis (PCA) were employed.
View Article and Find Full Text PDFPhotosynthetic microbial fuel cell (PMFC) is a novel technology, which employs organic pollutants and organisms to produce electrons and biomass and capture CO by bio-reactions. In this study, a new PMFC was developed based on Synechococcus sp. as a biocathode, and dairy wastewater was used in the anode chamber.
View Article and Find Full Text PDFRapid industrialization and urbanization have resulted in environmental pollution and unsustainable development of cities. The concentration of 12 potentially toxic metal(loid)s in windowsill dust samples (n = 50) were investigated from different functional areas of Qom city with the highest level of urbanization in Iran. Spatial analyses (ArcGIS 10.
View Article and Find Full Text PDFThe current research proposed a method for optimally combining feed input ratios in order to improve the quantity and quality of daily biogas production through optimizing the variable response level in the Taguchi method. The anaerobic digestion (AD) process of an existing plant in Iran was simulated through a set of two-stage pilot reactors under mesophilic temperature conditions in order to achieve optimal operational performance. Three common substrates (organic fraction of municipal solid wastes, fruit and vegetable wastes, and horse manure) along with two recirculated materials; the post-digestion sludge and the secondary digester slurry, were investigated in 16 experimental runs based on four different pre-surface hypotheses.
View Article and Find Full Text PDFThe efficacy of land-use changes on aquatic ecosystems has been extensively studied in recent decades. Water resource management needs to understand the relationship between land-use change patterns and water quality, especially in urban areas. Hence, recognizing spatial-temporal changes in land use is required for sustainable development and proper water resource management.
View Article and Find Full Text PDFThis study aimed to measure and ecologically assess heavy metals, including As, Cr, Pb, Cd, and Ni in water and sediment samples taken from Gomishan, an international wetland located in Golestan, Iran. Four sampling stations were selected to cover all parts of the wetland. The analyses of the heavy metals were performed by ICP-MS.
View Article and Find Full Text PDFSurface runoff is the most significant source of water in dry cities like Tehran. The surface runoff is polluted by heavy metals, which their risk level is a function of their speciation. Herein, Tehran runoff quality and the speciation of metals and metalloids were investigated.
View Article and Find Full Text PDFSediments are capable of adsorbing and desorbing heavy metals (HMs) under various environmental conditions. This study investigated the impact of pre-set redox potential (Eh) on the release dynamics of HMs (Co, Cr, Cu, Ni, Pb, V, and Zn) from sediment in an automated biogeochemical microcosm. The release of Co, Pb, and V under reducing conditions increased that may increase the potential risks in the aquatic environment.
View Article and Find Full Text PDFThe spatial and temporal distribution pattern is an outstanding feature of the relationship among ecosystem services (ESs) that explains links between human activities and disturbed chemical composition of ecosystems. This study investigated the spatiotemporal variation of land use/cover changes (LUCC) and quantifies the change in four essential ecosystem services with an emphasis on soil (nutrient delivery ratio, carbon storage, crop production, and water yield) and their relationships in the Jiroft plain, Iran, during 1996-2016 through analytical tools including Land Change Modeler, and the Integrated Valuation of Ecosystem Services and Tradeoff. During the 20-year concentrate period, there was a considerable overall gain in cropland (5396 km) and urban (1787 km), loss of unused land (5692 km), water (2088 km), and forest (1083 km).
View Article and Find Full Text PDFIn this study, we investigated the total arsenic concentration in the soil and the related human exposure risks in the central part of the Bardsir Plain in southeastern Iran. The results show that the average total arsenic concentration in agricultural soil is 50.26 mg/kg, which is 2.
View Article and Find Full Text PDFMultivariate statistical techniques and geostatistical methods are among the important tools used in surface water quality management. They are widely used in interpreting data, identifying the pollution sources, understanding the spatial variation of parameters, and determining the places of monitoring stations. Therefore, in this study, spatial variation of water quality and pollutants in the Anzali Wetland water (Iran) was evaluated using multivariate statistical and Kriging methods.
View Article and Find Full Text PDFDue to population growth and the considerable increase in usage of the resources, Human environment quality has been highly threatened by pollutants in recent decades. Polycyclic aromatic hydrocarbons (PAHs) are widespread, persistent organic pollutants which are of great concern due to their carcinogenicity. The present study is the first investigation that assesses contamination, sources and cancer risk of 16 priority PAHs proposed by US EPA in urban dust samples (n = 80) taken in different land-uses of Tehran metropolis, the capital of Iran.
View Article and Find Full Text PDFPollution levels of potentially toxic metals (PTMs) were studied performing enrichment factor, geo-accumulation index and ecological risk index. The most enriched elements which categorize as very high and extremely high enriched in different land-uses were in order of: commercial Cu (73.79)>Hg (66.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
February 2019
Annually, a great volume of sediment and suspended particulate matters (SPMs) enters into the seas through estuaries. In the estuarine zone, metals present in SPMs may undergo conservative or non-conservative changes. In the present study, oxidation-reduction potential (ORP) as the most complex chemical parameter of open sea water and its relationship with the behavior of t metals in the estuarine area were investigated.
View Article and Find Full Text PDFThe purpose of this article is to study, result of metal concentration in two-sediment cores from Persian Gulf. Age of sediment is determined by C isotope method and bulk concentration is determined by ICP. This research output shows that, age of BandareAbbas core back to 9660 and Bushehr core to 15,600 years ago.
View Article and Find Full Text PDFIn this study, an efficient adsorbent was proposed for the removal of mercury from saline water contaminated with mercury ions. FeO nanoparticles were modified using tetraethylenepentamine and carbon disulfide to incorporate dithiocarbamate functional group on the surface of the adsorbent. CHNS analysis confirmed successful modification of magnetic nanoparticles.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
December 2017
Metals are among the most common environmental pollutants, and their presence in high concentration in waters and biota have devastating effects on flora, fauna, and human health. Flocculation process of metals during estuarine mixing can reduce the environmental hazards of metals and also can provide micronutrients to the aquatic system. The present investigation provides a thorough study of eliminating colloidal elements of copper, manganese, nickel, lead, and zinc during estuarine mixing of Shalmanrood River water with Caspian Sea water in Iran.
View Article and Find Full Text PDFThe purpose of modification of magnetic iron oxide nanoparticles is an eco-friendly, emerging and economical method for removing deltamethrin in the aqueous solution and wastewater effluents when compared with other adsorbent methods. Modified magnetic iron oxide nanoparticles were synthesized by co-precipitation and then coupled with 3-hydroxytyraminium chloride. The nano-sorbent was characterized by thermogravimetric analysis, elemental analysis, transmission electron microscopy, scanning electron microscope, Fourier transform infrared spectroscopy, zero point charge and surface area determination.
View Article and Find Full Text PDFWater quality management plans are an indispensable strategy for conservation and utilization of water resources in a sustainable manner. One common industrial use of water is aquaculture. The present study is an attempt to use statistical analyses in order to prepare an environmental water quality monitoring program for Haraz River, in Northern Iran.
View Article and Find Full Text PDFSimilar to natural filters, estuaries are capable of removing considerable amounts of heavy metal from rivers that flow into saline water environments by turning the metal into flocs. The research objective was to investigate the self-purification potential of estuaries in removal of metal by flocculation processes. Hence, flocculation of metal was studied experimentally in 5 aquaria with varying salinity levels.
View Article and Find Full Text PDFBackground: One of the key issues in determining the quality of water in rivers is to create a water quality control network with a suitable performance. The measured qualitative variables at stations should be representative of all the changes in water quality in water systems. Since the increase in water quality monitoring stations increases annual monitoring costs, recognition of the stations with higher importance as well as main parameters can be effective in future decisions to improve the existing monitoring network.
View Article and Find Full Text PDF