Ag NPs decorated on the magnetic rod-like hydroxyapatite/MIL-101(Fe) nanocomposite as an efficient catalyst for the reduction of some nitroaromatic compounds and as an effective antimicrobial agent.

A rod-like magnetic nanocomposite was successfully synthesized in this work by loading Ag and FeO nanoparticles onto the surface of the hydroxyapatite/MIL-101(Fe) metal-organic framework. Various techniques were used to investigate the crystalline nature, size, morphology, and magnetic and structural properties of the HAP/MIL-101(Fe)/Ag/FeO nanocomposite, including X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, Raman spectroscopy, field-emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM), vibrating sample magnetometry (VSM), BET surface area measurements, and zeta potential analysis. The results indicate that the nanocomposite sample is composed of Ag and FeO nanoparticles adhered to rod-like hydroxyapatite/MIL-101(Fe).