3D tribo-nanoprinting using triboreactive materials.

Tribology: the science of friction, wear and lubrication has never been associated in a positive way with the ability to manufacture at the nanoscale. Triboreactivity, when the contact between two surfaces promotes a chemical reaction, has been harnessed in this study to create highly tenacious nano-features. The reported 3D tribo-nanoprinting methodology has been demonstrated for organic and inorganic fluids on steel and silicon substrates and is adaptable through the interface tribology.

On the Transient Decomposition and Reaction Kinetics of Zinc Dialkyldithiophosphate.

Despite the ubiquitous use of the zinc dialkyldithiophosphate (ZDDP) as an antiwear additive, no complete information is yet available on its exact decomposition reactions and kinetics to form triboreactive protective films on contacting surfaces. This hinders the replacement of ZDDP with more environmentally friendly additives of similar antiwear capabilities. Using a multitechnique approach, this study shows that before the formation of a phosphate-rich protective film, the decomposition of ZDDP proceeds by forming intermediate zinc sulfide and sulfate species, which can be mechanically mixed with the iron oxides on the rubbing steel surfaces.

synchrotron XAS study of the decomposition kinetics of ZDDP triboreactive interfaces.

One of the major obstacles in replacing the widely used zinc dialkyldithiophosphate (ZDDP) antiwear additive with a more environmentally friendly one is the difficulty of time-resolving the surface species resulting from its decomposition mechanism under high contact pressure and temperature. To tackle this issue, a newly developed miniature pin-on-disc tribotester was coupled with synchrotron X-ray absorption spectroscopy (XAS) to perform tribological tests while examining the composition of the formed triboreactive films. The results showed that in the case of bare steel surfaces the initial decomposition products are mainly zinc sulfate species, which with further shearing and heating are reduced to zinc sulfide mixed with metal oxides.