as a new low-cost adsorbent for water treatment: highly effective adsorption of crystal violet.

Synthetic dyes are prevalent in aquatic environments, they have high toxicities, are non-degradable, and accumulate in the water. The removal of Crystal violet (CV) is carried out using batch experiments on the Salsola Tetragona (ST) plant as a novel adsorbent. The prepared adsorbent was analyzed by various methods (MEB, EDX, IRTF and PZC), to support its applicability as adsorbent.

Polyaniline coated tungsten trioxide as an effective adsorbent for the removal of orange G dye from aqueous media.

In this work, the core-shell PANI@WO composite was obtained from the reaction of aniline monomer polymerization with WO particles; sodium persulfate was used as an oxidant. Various analytical techniques such as scanning electron microscopy (SEM-EDS), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Brunauer-Emmett-Teller (BET), and X-ray photoelectron spectroscopy (XPS) were used to characterize the as-prepared PANI@WO adsorbent, which well confirmed that the WO particles were coated by polyaniline polymer. The PANI@WO composite was tested as an adsorbent to remove reactive orange G (OG) for the first time.

Application of calcium alginate-PANI@sawdust wood hydrogel bio-beads for the removal of orange G dye from aqueous solution.

This work aims to investigate the adsorption performance of orange G (OG) dye from aqueous solutions employing PANI@sawdust biocomposite enrobed by calcium-alginate bio-beads (Alg-PANI@SD). The as-prepared adsorbent was characterized by scanning-electron-microscopy (SEM), X-ray energy-dispersive spectroscopy (EDS), and Fourier transforms infrared (FT-IR) spectroscopy and used to remove orange G dye from aqueous water. Batch tests were performed as a function of adsorbent dosage, pH, contact time, interfering ions, and initial OG dye concentration.

Effectiveness of a novel polyaniline@Fe-ZSM-5 hybrid composite for Orange G dye removal from aqueous media: Experimental study and advanced statistical physics insights.

A polyaniline@Fe-ZSM-5 composite was synthesized via an in situ interfacial polymerization procedure. The morphology, crystallinity, and structural features of the as-developed PANI@Fe-ZSM-5 composite were assessed using scanning electron microscopy - energy dispersive spectroscopy (SEM-EDS), X-ray diffraction (XRD), Fourier-transform infrared (FTIR) spectroscopy, and X-ray photoelectron spectroscopy (XPS). The composite was efficiently employed for the first time as an adsorbent Orange G (OG) dyestuff from water.

Efficient removal of crystal violet dye from aqueous solutions using sodium hydroxide-modified avocado shells: kinetics and isotherms modeling.

The main objective of this study is to optimize a new composite for the depollution of contaminated water. The sodium hydroxide-modified avocado shells (NaOH-AS) were firstly prepared, characterized by field-emission-scanning-electron-microscopy (FE-SEM), X-ray energy dispersive spectroscopy (EDS) and Fourier transforms infrared (FT-IR) spectroscopy, and applied for efficient removal of crystal violet dye (CV) in wastewater. In addition, the adsorption in a batch system of CV dye on the NaOH-AS material was studied.

Comparison of green bio-based cerium/alginate vs. copper/alginate beads: a study of vibrational and thermal properties using experimental and theoretical methods.

Herein, bio-based alginates (Alg) containing metallic beads (Ce and Cu) were synthesized via an alginate cross-linking method, and their properties were studied using experimental techniques combined with theoretical simulations. Materials were characterized through Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), and scanning electron microscope (SEM) images, to determine the cross-linking structural features, thermal stability, and surface morphology of alginates. Besides, density functional theory (DFT) methods were employed to calculate global reactivity parameters such as HOMO-LUMO gap energies (ΔE), electronegativity (χ), hardness (η), and electrophilic and nucleophilic indicators, using both gas and aqueous media for the study of the complexation process.

Synthesis and characterization of arginine-doped heliotrope leaves with high clean-up capacity for crystal violet dye from aqueous media.

A novel arginine-modified Heliotrope leaf (Arg@HL) was used as adsorbent for the crystal violet (CV) dye adsorption in a batch process. The physicochemical and morphological composition of Arg@HL were characterized by field-emission scanning electron microscopy (FE-SEM), Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). The experiments were carried out to investigate the factors that influence the dye uptake by the adsorbent, such as the contact time under agitation, adsorbent amount, initial dye concentration, temperature and pH of dye solution.

Efficient detoxification of Cr(VI)-containing effluents by sequential adsorption and reduction using a novel cysteine-doped PANi@faujasite composite: Experimental study supported by advanced statistical physics prediction.

Nowadays, the global spreading of hazardous heavy metals becomes a top-priority environmental challenge, owing to its serious detrimental health outcomes. Herein, a novel cysteine-doped polyaniline@faujasite hybrid composite (Cys-PANi@FAU-50) was synthesized via a facile in-situ polymerization route for the effective detoxification of Cr(VI)-bearing wastewaters. The Cys-PANi@FAU-50 composite displayed an open mesoporous structure richly decorated with nitrogen/oxygen-containing functional groups, which consequently boosted the diffusion, adsorption and reduction of Cr(VI) oxyanions.

Facile synthesis and characterization of a novel 1,2,4,5-benzene tetracarboxylic acid doped polyaniline@zinc phosphate nanocomposite for highly efficient removal of hazardous hexavalent chromium ions from water.

The present study describes the preparation of a novel 1,2,4,5-benzene tetracarboxylic acid doped polyaniline@zinc phosphate (BTCA-PANI@ZnP) nanocomposite via a facile two-step procedure. Thereafter, the as-prepared composite material adsorption characteristics for Cr(VI) ions removal were evaluated under batch adsorption. Kinetic approach studies for Cr(VI) removal, clearly demonstrated that the results of the adsorption process followed the pseudo second order and Langmuir models.

Novel citric acid-functionalized brown algae with a high removal efficiency of crystal violet dye from colored wastewaters: insights into equilibrium, adsorption mechanism, and reusability.

Synthetic dye waste is one of the world's key ecological concerns. The algal biomass has emerged as a promising alternative adsorbent for wastewater treatment. The present study deals with the functionalization of brown algae (BA) by citric acid in order to improve its adsorption ability for textile dye removal in aqueous solutions.

Elaboration of novel polyaniline@Almond shell biocomposite for effective removal of hexavalent chromium ions and Orange G dye from aqueous solutions.

A novel polyaniline@Almond shell (PANI@AS) biocomposite was synthesized via facile in situ chemical polymerization method. The as-synthesized adsorbent was characterized using various analytical techniques such as Fourier transform infrared spectroscopy (FTIR), X-ray energy dispersive spectroscopy (EDS), scanning electron microscopy (SEM), and potentiometric titration. A batch adsorption system was applied with the aim of investigating as-synthesized adsorbent ability to remove Cr(VI) ions and Orange G (OG) textile dye from aqueous solutions.