Carob fruit extract as naturally products corrosion inhibitor for copper-nickel alloys in brine solutions.

Copper-nickel alloys are the preferred material for desalination facilities and condensers and heat exchangers that use saltwater as a coolant. The eco-friendly compounds especially Carob fruit extract (CFE) has emerged as excessive green corrosion inhibitor for alloys. Cu-Ni alloys are widely used in various industries due to their excellent corrosion resistance.

Eco-friendly impact of a novel green extract as a sustainable inhibitor to reduce acid corrosion of copper.

In this study, we deployed green extract (MOE) as a corrosion inhibitor for copper. The anticorrosion properties of MOE for Cu in 1 M HNO were investigated by various experimental and numerical techniques, including potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS), and a weight loss (WL) method at different temperatures. Additionally, scanning electron microscopy (SEM) coupled with energy-dispersive X-ray analysis (EDX) and atomic force microscopy (AFM) were utilized to examine the surface morphology of Cu with and without the extract.

Synergistic inhibition effect of diolefinic dye and silver nanoparticles for carbon steel corrosion in hydrochloric acid solution.

The current work looks at the inhibitory effects of a diolefinic dye, namely 1,4-bis((E)-2-(3-methyl-2,3-dihydrobenzo[d]thiazol-2-yl) vinyl) benzene iodide salt, in relation to CS corrosion mitigation in hydrochloric acid (HCl) environment. This study uses a variety of experimental methodologies, including weight loss (WL) analysis, electrochemical tests, and theoretical considerations. The synergistic effect of diolefinic dye and AgNPs on the corrosion inhibition of CS in 1 M HCl was investigated.

Synthesis of new binary trimethoxyphenylfuran pyrimidinones as proficient and sustainable corrosion inhibitors for carbon steel in acidic medium: experimental, surface morphology analysis, and theoretical studies.

In this study, synthesis and assessment of the corrosion inhibition of four new binary heterocyclic pyrimidinones on CS in 1.0 M hydrochloric acid solutions at various temperatures (30-50 °C) were investigated. The synthesized molecules were designed and synthesized through Suzuki coupling reaction, the products were identified as 5-((5-(3,4,5-trimethoxyphenyl)furan-2-yl)methylene)pyrimidine-2,4,6(1H,3H,5H)-trione (HM-1221), 2-thioxo-5-((5-(3,4,5-trimethoxyphenyl)furan-2-yl)methylene)dihydropyrimidine-4,6(1H,5H)-dione (HM-1222), 1,3-diethyl-2-thioxo-5-((5-(3,4,5-trimethoxyphenyl)furan-2-yl)methylene)dihydropyrimidine-4,6(1H,5H)-dione (HM-1223) and 1,3-dimethyl-5-((5-(3,4,5-trimethoxyphenyl)furan-2-yl)methylene)pyrimidine-2,4,6(1H,3H,5H)-trione (HM-1224).

Application of lentil seed extract as an inhibitor to assess the corrosion properties of copper-nickel alloys in a NaCl environment.

Weight loss (WL), electrochemical, and surface analysis were used to explore the efficiency of lentil seed extract (LSE) in mitigating the electrochemical corrosion of Cu-10Ni and Cu-30Ni alloys in obviously aerated water. The adsorption of lentil seed extract (LSE) species to create a barrier layer improved the corrosion resistance of Cu-Ni alloys in a NaCl medium. It was shown that the temperature of the medium and the amount of extract used affected the enhanced inhibitory efficacy.

Verbena officinalis (VO) leaf extract as an anti-corrosion inhibitor for carbon steel in acidic environment.

In the present work, Verbena Officinalis (VO) leaf extract was used as potential corrosion inhibitor for the corrosion of carbon steel (CS) in 0.5 M HSO medium. Further, the corrosion inhibiting nature of VO leaf extract towards the CS was evaluated using mass loss (ML), potentiodynamic polarization (PDP), electrical impedance spectroscopy (EIS) and surface morphological analyses using atomic force microscope (AFM) and X-ray photoelectron spectroscopy (XPS) techniques.

Expression of concern: Effectiveness of some novel heterocyclic compounds as corrosion inhibitors for carbon steel in 1 M HCl using practical and theoretical methods.

Expression of concern for 'Effectiveness of some novel heterocyclic compounds as corrosion inhibitors for carbon steel in 1 M HCl using practical and theoretical methods' by Abd El-Aziz S. Fouda , , 2021, , 19294-19309, https://doi.org/10.

Expression of concern: Experimental and surface morphological studies of corrosion inhibition on carbon steel in HCl solution using some new hydrazide derivatives.

Expression of concern for 'Experimental and surface morphological studies of corrosion inhibition on carbon steel in HCl solution using some new hydrazide derivatives' by Abd El-Aziz S. Fouda , , 2021, , 13497-13512, https://doi.org/10.

Experimental and theoretical studies of the efficiency of metal-organic frameworks (MOFs) in preventing aluminum corrosion in hydrochloric acid solution.

Aluminum corrosion inhibitors "{[CuI (CN)(phen) CuII (CN)(phen)]5HO},(MOF1) and {[CuI(CN)(phen)CuII(CN)(phen)]5HO}@TiO (MOF1@TiO) were studied in one molar HCl solution". The ML results for three different temperatures (25-45 °C) were compared with the results of PDP and EIS analyses. The adsorption of inhibitors on Al surfaces has been calculated and discussed by a Langmuir isotherm.

Synthesis and Characterization of New Polymeric Ionic Liquids as Corrosion Inhibitors for Carbon Steel in a Corrosive Medium: Experimental, Spectral, and Theoretical Studies.

A novel series of polymeric ionic liquids (ILs) based on benzimidazolium chloride derivatives, namely, 1,3-diheptyl-2-(2-phenyl-propyl)-3-benzimidazol-1-ium chloride (IL1), 1,3-dioctyl-2-(2-phenyl-propyl)-3-benzimidazol-1-ium chloride (IL2), and 1,3-Bis-decyl-2-(2-phenyl-propyl)-3-benzoimidazol-1-ium chloride (IL3), were synthesized and chemically elucidated by Fourier transform infrared spectroscopy, H NMR, C NMR, and elemental analysis. Their influence as corrosion suppressors were investigated for C-steel corrosion in 1 M HCl, by weight loss (WL), potentiodynamic polarization (PDP), and electrochemical impedance spectroscopy (EIS) methods, revealing that their exclusive addition decreased corrosion with mounting concentrations. These assays demonstrated that novel ILs are efficient inhibitors at relatively low dosages.

Synthesis of inventive biphenyl and azabiphenyl derivatives as potential insecticidal agents against the cotton leafworm, Spodoptera littoralis.

The emergence of pest resistance of Spodoptera littoralis (order; Lepidoptera, family; Noctuidae) towards the large scale of different classes of insecticides necessitates the development of some new poly-functionalized biphenyl and azabiphenyl with highly anticipated insecticidal bioresponse. Four new biphenyl carboxamidines 4a-d and four aza-analogue picolinamidine derivatives 8a-d were designed and prepared via the treatment of their corresponding carbonitriles with lithium-bis trimethylsilylamide [LiN(TMS)], followed by hydrolysis with hydrogen chloride. Furthermore, these compounds were elucidated by spectral data, and their toxicity and insecticidal activity were screened against Spodoptera littoralis.

Synthesis and Characterization of a Novel Quaternary Ammonium Salt as a Corrosion Inhibitor for Oil-Well Acidizing Processes.

A quaternary ammonium salt, 1,1'-(1,4-phenylenebis(methylene))bis(4-formylpyridin-1-ium) (PMBF), was synthesized, characterized, and investigated as an inhibitor for C1018 (type steel in oil wells) corrosion in 17.5% HCl solution. The chemical structure of PMBF was confirmed using altered techniques.

A fruitful century for the scalable synthesis and reactions of biphenyl derivatives: applications and biological aspects.

This review provides recent developments in the current status and latest synthetic methodologies of biphenyl derivatives. Furthermore, this review investigates detailed discussions of several metalated chemical reactions related to biphenyl scaffolds such as Wurtz-Fittig, Ullmann, Bennett-Turner, Negishi, Kumada, Stille, Suzuki-Miyaura, Friedel-Crafts, cyanation, amination, and various electrophilic substitution reactions supported by their mechanistic pathways. Furthermore, the preconditions required for the existence of axial chirality in biaryl compounds are discussed.

Experimental and computational approaches of methoxy naphthylbithiophene derivatives and their use as corrosion protection for carbon steel in acidic medium.

The inhibition efficiency and adsorption affinity were investigated for two novel compounds, namely: 6-methoxy-2-naphthyl-[2, 2'-bithiophene]-5-carboxamidine hydrochloride salt (MA-1440) and 5'-(4-chlorophenyl)-2, 2'-bifuran-5-carboxamidine hydrochloride salt (MA-1456). The inhibition study was conducted on carbon steel surface in 1.0 M HCl with different inhibitor doses and different temperature levels, to investigate the optimum dose and preferable temperature.

Insights into the adsorption and corrosion inhibition properties of newly synthesized diazinyl derivatives for mild steel in hydrochloric acid: synthesis, electrochemical, SRB biological resistivity and quantum chemical calculations.

Two azo derivatives, 4-((4-hydroxy-3-((4-oxo-2-thioxothiazolidin-5-ylidene)methyl)phenyl) diazinyl) benzenesulfonic acid (TODB) and 4-((3-((4,4-dimethyl-2,6-dioxocyclohexylidene) methyl)-4-hydroxyphenyl)diazinyl) benzenesulfonic acid (DODB) were synthesized and characterized using Fourier-transform infrared spectroscopy (FTIR), proton nuclear magnetic resonance (H-NMR) and mass spectral studies. Gravimetric methods, potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS), electrochemical frequency modulation (EFM) techniques and inductive coupled plasma-optical emission spectroscopy were used to verify the above two compounds' ability to operate as mild steel (MS) corrosion inhibitors in 1 M HCl. Tafel data suggest that TODB and DODB have mixed-type characteristics, and EIS findings demonstrate that increasing their concentration not only alters the charge transfer ( ) of mild steel from 6.

Aizoon extract as an eco-friendly corrosion inhibitor for stainless steel 430 in HCl solution.

Aizoon extract is used as an eco-friendly anti-corrosive material for stainless steel 430 (SS430) in a 2 M hydrochloric acid solution. Many strategies were utilized to estimate the mitigation efficacy such as mass reduction (MR), electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization (PDP). The inhibition percentage (%) increases by increasing the concentration of Aizoon and reaches 95.

Corrosion mitigation for steel in acid environment using novel -phenylenediamine and benzidine coumarin derivatives: synthesis, electrochemical, computational and SRB biological resistivity.

Three novel -phenylenediamine and benzidine coumarin derivatives were synthetized, namely: 4,4'-((((1,4-phenylenebis(azaneylylidene))bis(ethan-1-yl-1-ylidene))bis(2-oxo-2-chromene-3,6-diyl))bis(diazene-2,1-diyl))dibenzenesulfonic acid (PhODB), 4,4'-(((-([1,1'-biphenyl]-4,4'-diylbis(azaneylylidene))bis(ethan-1-yl-1-ylidene))bis(2-oxo-2-chromene-3,6-diyl))bis(diazene-2,1-diyl))dibenzenesulfonic acid (BODB) and 4,4'-(((-((3,3'-dimethoxy-[1,1'-biphenyl]-4,4'-diyl)bis(azaneylylidene))bis(ethan-1-yl-1-ylidene))bis(2-oxo-2-chromene-3,6-iyl))bis(diazene-2,1-diyl))dibenzenesulfonic acid (DODB). Their chemical structures were proved by performing Fourier-transform infrared spectroscopy, proton nuclear magnetic resonance and mass spectrometry analysis. The synthesized -phenylenediamine and benzidine coumarin derivatives were tested as corrosion inhibitors for mild steel (MS) in 1 M HCl solution using weight loss, electrochemical, morphological, and theoretical studies.

Novel pyrimidine-bichalcophene derivatives as corrosion inhibitors for copper in 1 M nitric acid solution.

This study targets the investigation of three pyrimidine-bichalcophene derivatives (MA-1230, MA-1231, MA-1232) for the prevention of corrosion on copper in 1 M HNO weight loss (WL), potentiodynamic polarization (PDP), and electrochemical impedance spectroscopy (EIS) techniques. The surface morphology was also analyzed by different methods. It was found that the inhibition efficiency (% ) increased by increasing the doses of pyrimidine derivatives and the temperature of the medium.

Effectiveness of some novel heterocyclic compounds as corrosion inhibitors for carbon steel in 1 M HCl using practical and theoretical methods.

Corrosion of carbon steel is a major problem that destroys assists of industries and world steel installations; the importance of this work is to introduce new heterocyclic compounds as effective and low-cost corrosion inhibitors. Three compounds of carbohydrazide derivatives, namely: 5-amino-'-((2-methoxynaphthalen-1-yl)methylene)isoxazole-4-carbohydrazide (H4), 2,4-diamino-'-((2-methoxy-naphthalene-1-yl)methylene) pyrimidine-5-carbohydrazide (H5) and '-((2-methoxynaphthalen-1-yl)methylene)-7,7-dimethyl-2,5-dioxo-4,5,6,7,8,8-hexahydro-2-chromene-3-carbohydrazide (H6) were used to examine the efficacy of corrosion of carbon steel in 1 M hydrochloric acid solution. This corrosion efficacy was detected by utilizing various methods including electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (PDP), weight loss measurements (WL), surface morphology analyses by atomic force microscopy (AFM), quantum chemical computations based on density functional theory (DFT) and molecular dynamics (MD) simulation.

Electrochemical and quantum chemical studies on the corrosion inhibition of 1037 carbon steel by different types of surfactants.

In this work, three different types of surfactants, namely, dodecyl trimethyl ammonium chloride (DTAC, CHN (CH)Cl), octyl phenol poly(ethylene glycol ether) (TX-100, CHO for = 10) and dioctyl sodium sulfosuccinate (AOT-100, CHONaS) with corrosion restraint were utilized as corrosion inhibitors for 1037 CS in 0.5 M HCl. The protection efficacy (% IE) was indicated by weight loss and electrochemical measurements.

5-Arylidene-1,3-dialkylbarbituric acid derivatives as efficient corrosion inhibitors for carbon steel in molar hydrochloric acid solution.

The inhibiting impact of two ecofriendly 5-arylidene barbituric acid derivatives (5-ABA), namely 5-(3,4-dimethoxybenzylidene)-1,3-dimethylpyrimidine-2,4,6(1,3,5)-trione (inhibitor I, 3a) and 5-(3,4-dimethoxybenzylidene)-1,3-diethyl-2-thioxodihydropyrimidine-4,6(1,5)-dione (inhibitor II, 3b), in 1 M HCl on the corrosion of carbon steel has been examined the weight loss (WL) method, potentiodynamic polarization (PP), electrochemical impedance spectroscopy (EIS), and electrochemical frequency modulation (EFM) tests. In addition, DFT calculations and MC simulations were used to study the relationship between the inhibitor structure and its inhibition performance. The attained outcomes exhibit that the investigated compounds are excellent inhibitors and their inhibition efficiency (%IE) increases with the increase in the concentration and temperature.

Experimental and surface morphological studies of corrosion inhibition on carbon steel in HCl solution using some new hydrazide derivatives.

The corrosion inhibition of C-steel in 1 M HCl was assessed using three newly synthesized hydrazide derivatives (H1, H2 and H3) using weight loss (WL), potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) techniques. Also, the adsorption of these compounds was confirmed using several techniques such as atomic force microscopy (AFM), Fourier-transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS). High inhibition efficiencies were obtained resulting from the constitution of the protective layer on the C-steel surface, which increased with increasing concentration and temperature and reached 91.

Experimental and computational chemical studies on the corrosion inhibitive properties of carbonitrile compounds for carbon steel in aqueous solutions.

The present work aims to study 6-amino-4-aryl-2-oxo-1-phenyl-1,2-dihydropyridine-3,5-dicarbonitrile derivatives namely: 6-Amino-2-oxo-1,4-diphenyl-1,2-dihydropyridine-3,5-dicarbonitrile (PdC-H), 6-Amino-2-oxo-1-phenyl-4-(p-tolyl)-1,2-dihydropyridine-3,5-dicarbonitrile (PdC-Me) and 6-Amino-4-(4-hydroxyphenyl)-2-oxo-1-phenyl-1,2-dihydropyridine-3,5-dicarbonitrile (PdC-OH) as corrosion inhibitors to provide protection for carbon steel in a molar hydrochloric acid medium. Chemical measurements such as (weight loss) and electrochemical techniques such as (Potentiodynamic polarization, electrochemical impedance spectroscopy, and Electron frequency modulation) were applied to characterize the inhibitory properties of the synthesized derivatives. The adsorption of these derivatives on the carbon steel surface was confirmed by Attenuated Total Refraction Infrared (ATR-IR), Atomic Force Microscope (AFM), and X-ray Photoelectron Spectroscopy (XPS).

Chemical, electrochemical and surface studies of new metal-organic frameworks (MOF) as corrosion inhibitors for carbon steel in sulfuric acid environment.

The effects of [Co (SCN) 4(hmt)(HO). HO] (SC1) and [Co (CN) (MeSn)(HO). (qox)] (SCP2) MOF as corrosion inhibitors on C-steel in 0.