Surface characterisation of chemically reduced electrolytic manganese dioxide.

In this work a titration technique has been used to characterize the amphoteric surface properties of a series of chemically reduced electrolytic manganese dioxide (EMD) samples (MnO 1.97 to MnO 1.50).

Surface characterization of heat-treated electrolytic manganese dioxide.

In this work a titration technique was used to determine the amphoteric surface properties of a series of heat-treated electrolytic manganese dioxide (EMD) samples (up to 500 degrees C). The surface of each sample was found to consist of independent acidic and basic hydroxyl sites, which could be characterized by their respective equilibrium constants and site concentrations. It was found that the acidic sites could not be characterized by a single equilibrium constant, but rather by a distribution indicating the subtle differences between individual sites, while a single equilibrium constant adequately represented the basic sites.