J Phys Condens Matter
November 2017
Upon thermal annealing at or above room temperature (RT) and at high hydrostatic pressure P ~ 155 GPa, sulfur trihydride HS exhibits a measured maximum superconducting transition temperature T ~ 200 K. Various theoretical frameworks incorporating strong electron-phonon coupling and Coulomb repulsion have reproduced this record-level T . Of particular relevance is that experimentally observed H-D isotopic correlations among T , P, and annealed order indicate an H-D isotope effect exponent α limited to values ⩽ 0.
View Article and Find Full Text PDFJ Phys Condens Matter
April 2017
Unique among alkali-doped A C fullerene compounds, the A15 and fcc forms of CsC exhibit superconducting states varying under hydrostatic pressure with highest transition temperatures at [Formula: see text] = 38.3 and 35.2 K, respectively.
View Article and Find Full Text PDFIn a recent contribution to this journal, it was shown that the transition temperatures of optimal high-T(C) compounds obey the algebraic relation T(C0) = k(-1)(B)/ℓζ, where ℓ is related to the mean spacing between interacting charges in the layers, ζ is the distance between interacting electronic layers, β is a universal constant and k(B) is Boltzmann's constant. The equation was derived assuming pairing based on interlayer Coulomb interactions between physically separated charges. This theory was initially validated for 31 compounds from five different high-T(C) families (within an accuracy of ±1.
View Article and Find Full Text PDFMuon spin rotation (μ(+)SR) measurements of square-root second moments of local magnetic fields σ in superconducting mixed states, as published for oriented crystals and powder samples of YBa(2)Cu(3)O(7 - δ) (δ≈0.05), YBa(2)Cu(4)O(8) and La(2 - x)Sr(x)CuO(4) (x ∼ 0.15-0.
View Article and Find Full Text PDFPhys Rev B Condens Matter
February 1993
The temperature- and concentration-dependent resistivities of annealed CaxC(60) and SrxC(60) films were measured near room temperature. Resistivity minima were observed at x = 2 and 5. The resistivities of these films were rho(min) approximately 1 ohm-centimeter for x = 2 and rho(min) approximately 10(-2) ohm-centimeter for x = 5.
View Article and Find Full Text PDFElectrical resistances of polycrystalline fullerene (C(60)) films were monitored while the films were being doped in ultrahigh vacuum with potassium from a molecular-beam effusion source. Temperature- and concentration-dependent resistivities of K(chi) C(60) films in equilibrium near room temperature were measured. The resistance changes smoothly from metallic at chi approximately 3 to activated as chi --> = 0 or chi --> 6.
View Article and Find Full Text PDFPhys Rev B Condens Matter
March 1990
Phys Rev B Condens Matter
February 1990
Phys Rev B Condens Matter
January 1990
Phys Rev B Condens Matter
November 1988