Synthesis and Surface Properties of Photoresponsive Gemini Surfactants: Implication for Remediating PAHs-Contaminated Groundwater.

The efficient utility of surfactants remains a daunting task for groundwater remediation. In this study, we have synthesized a conventional photoresponsive surfactant 4-[4-[(4-butylphenyl)azo]phenoxy]butyldimethylethylammonium bromide (AzoPB) and a gemini photoresponsive surfactant ,-bis[4-[4-[(4-butylphenyl)azo]phenoxy]butyl]-,-tetramethylethane-1,2-diammonium bromide (AzoPBT) for solubilizing PAHs in groundwater. The two surfactants' photosensitivity, surface properties, and solubilization/release ability for phenanthrene (Phe) and acenaphthylene (Ace) were studied in detail.