Harmonizing Energies: The Interplay Between a Nonplanar SalEn-Type Molecule and a TEMPO Moiety in a New Hybrid Energy-Storing Redox-Conducting Polymer.

Redox-conducting polymers based on SalEn-type complexes have attracted considerable attention due to their potential applications in electrochemical devices. However, their charge transfer mechanisms, physical and electrochemical properties remain unclear, hindering their rational design and optimization. This study aims to establish the influence of monomer geometry on the polymer's properties by investigating the properties of novel nonplanar SalEn-type complexes, poly[N,N'-bis(salicylidene)propylene-2-(hydroxy)diaminonickel(II)], and its analog with 2,2,6,6-tetramethylpiperidinyl-N-oxyl (TEMPO)-substituted bridge (MTS).

Optimization of Printing Parameters to Enhance Tensile Properties of ABS and Nylon Produced by Fused Filament Fabrication.

This study aimed to identify the optimum printing parameters for the fused filament fabrication (FFF) of acrylonitrile butadiene styrene (ABS) and polyamide (nylon), to improve strength properties. For this purpose, the methodology of the paper involves an experimental study that used Taguchi's method to identify the effects of the infill pattern, infill density, and printing speed on the mechanical properties of the materials. ABS and nylon plastic parts were tested in tension to failure.

The Analysis of Stress Raisers Affecting the GFRP Strength at Quasi-Static and Cyclic Loads by the Theory of Critical Distances, Digital Image Correlation, and Acoustic Emission.

The purpose of this work is to analyze the stress-raisers that affect the tensile strength and fatigue resistance of GFRP parts using the point and line methods of the theory of critical distances (TCD) to obtain a quantitative measure of the defect size that can be tolerated by the composite before it fails. In the course of the work, a method combining TCD and the Weibull function was developed. In the course of the work, GFRP structural fiberglass for electrical purposes was tested under uniaxial quasi-static and cyclic loading with digital image correlation (DIC) and acoustic emission (AE), as well as a numerical simulation of deformation.

Optimization of Fatigue Performance of FDM ABS and Nylon Printed Parts.

This research work aims to proceed with the optimization of Fused Deposition Modeling (FDM) printing parameters for acrylonitrile butadiene styrene (ABS) and polyamide (Nylon) to improve fatigue resistance. For that purpose, the methodology of the paper involves two main approaches: experimental study and finite element analysis. The experimental part of the paper used the Taguchi method to find the effects of printing internal geometry, printing speed, and nozzle diameter on the fatigue life of ABS and Nylon plastic materials.

Tuning the Charge Transport in Nickel Salicylaldimine Polymers by the Ligand Structure.

The conductivity of the polymeric energy storage materials is the key factor limiting their performance. Conductivity of polymeric NiSalen materials, a prospective class of energy storage materials, was found to depend strongly on the length of the bridge between the nitrogen atoms of the ligand. Polymers obtained from the complexes containing C alkyl and hydroxyalkyl bridges showed an electrical conductivity one order of magnitude lower than those derived from more common complexes with C alkyl bridges.