Publications by authors named "A Yu Vasiliev"

Object: To evaluate inter- and intra-observer agreement of the proposed diagnostic and treatment classification of degenerative spondylolisthesis.

Material And Methods: The proposed diagnostic and treatment classification of degenerative spondylolisthesis was validated according to the GRRAS protocol. For this purpose, we retrospectively analyzed MRI, CT and spinal radiography data in 20 patients.

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Background: Bi is a short-lived radionuclide currently trialed for alpha therapy of various oncological diseases. A serious obstacle to the wide medical use is decay losses of Bi during a conventional synthesis of radiopharmaceuticals. In this work, we aimed to develop a two-column Aс/Bi generator providing the accumulation of Bi separately from the parent Ac via continuous circular separation and decay of intermediate Fr.

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In this paper, we present the synthesis and characterization of a rubidium vanadium(III) vanadyl(IV) phosphate, obtained under hydrothermal conditions. The new compound crystallizes in the triclinic space group 1̄ with the unit cell parameters = 9.637(1), = 12.

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Article Synopsis
  • A neutral iron(III) complex hydrate based on pyruvic acid thiosemicarbazone was synthesized and analyzed using various methods like FT-IR spectroscopy and X-ray diffraction, with its structure being reported for the first time.
  • The structure features an octahedron geometry around the Fe(III) ion formed by two ligands, resulting in unique interactions, including π-π interactions and hydrogen bonding.
  • Notably, the magnetic properties show a spin-crossover phenomenon at temperatures between 300-363 K, revealing weak antiferromagnetic exchange interactions between iron(III) centers, confirmed by theoretical calculations.
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The article presents a novel gas-chemical approach for Ac/Bi generators, which provides effective separation of Bi from parent Ac. The main problem with the generators of high activity is the radiation stability of sorbents, which is not substantial in this gas-chemical method of separation, where only radiationally stable inorganic materials are used. The approach includes heating at high temperature (about 900-1000 °C) Ac sample deposited on a backing material (Nb, quartz glass, stainless steel) in hydrogen-containing inert gas flow.

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