Publications by authors named "A Wittemann"

Complex structures can be understood as compositions of smaller, more basic elements. The characterization of these structures requires an analysis of their constituents and their spatial configuration. Examples can be found in systems as diverse as galaxies, alloys, living tissues, cells, and even nanoparticles.

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The structure formation and the phase behaviour of monolayers of dumbbell-shaped colloids are explored. For this, we conduct Langmuir-Blodgett experiments at the air/water interface and conventional Brownian dynamic simulations without hydrodynamic interactions. Using Voronoi tessellations and the probability density of the corresponding shape factor of the Voronoi cells p(ζ), the influence of the area fraction φ on the structure of the monolayers is investigated.

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Differential centrifugal sedimentation (DCS) is based on physical separation of nanoparticles in a centrifugal field prior to their analysis. It is suitable for resolving particle populations, which only slightly differ in size or density. Agglomeration presents a common problem in many natural and engineered processes.

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Density gradient centrifugation is an effective method for the isolation and purification of small particles. Hollow rotors capable of hosting density gradients replace the need for centrifuge tubes and therefore allow separations at large scales. So far, zonal rotors have been used for biological separations ranging from the purification of whole cells down to serum proteins.

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Understanding the hydrodynamics of colloids with complex shapes is of equal importance to widespread practical applications and fundamental scientific problems, such as gelation, crystallization, and phase behavior. Building on previous work, we present a comprehensive study of sedimentation, diffusion, intrinsic viscosities, and other shape-dependent quantities of clusters built from spherical nanoparticles. Cluster preparation is accomplished by assembling surface-modified polystyrene particles on evaporating emulsion droplets.

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