Publications by authors named "A Wain"

Perfluorinated sulfonic acid ionomers are well known for their unique water uptake properties and chemical/mechanical stability. Understanding their performance-stability trade-offs is key to realizing membranes with optimal properties. Terahertz time-domain spectroscopy has been demonstrated to resolve water states inside industrially relevant membranes, producing qualitatively agreeable results to conventional gravimetric analysis and prior demonstrations.

View Article and Find Full Text PDF

Lithium-ion batteries are the most ubiquitous energy storage devices in our everyday lives. However, their energy storage capacity fades over time due to chemical and structural changes in their components, via different degradation mechanisms. Understanding and mitigating these degradation mechanisms is key to reducing capacity fade, thereby enabling improvement in the performance and lifetime of Li-ion batteries, supporting the energy transition to renewables and electrification.

View Article and Find Full Text PDF
Article Synopsis
  • The study evaluates operando ATR-IR spectroscopy methods to analyze organoaluminate electrolytes for use in Mg batteries.
  • Using the "all-phenyl complex" in THF as a model, two spectroelectrochemical configurations are compared: one with a Pt gauze electrode and another with a thin Pt film on an ATR crystal.
  • The results show significant variations in ATR-IR responses due to the electrode arrangements, highlighting the advantages and challenges of each configuration.
View Article and Find Full Text PDF

We explore the use of femtosecond laser pulses to clean a variety of colors of spray paint from the Moruya granite, a stone with high heritage value that is widely used for monuments and sculptures in Sydney and New South Wales (Australia). The efficiency of the cleaning treatment and the effects on the stone substrate are evaluated using optical microscopy, optical profilometry, Raman spectroscopy, energy-dispersive X-ray spectroscopy, and colorimetry. We demonstrate that femtosecond laser cleans granite without damaging it and without discoloration when the laser fluence is set below the damage threshold of the stone.

View Article and Find Full Text PDF
Article Synopsis
  • The magnesium electrolyte, [MgCl][AlPh], is created through a ligand exchange reaction between AlCl and MgPh, making it a more environmentally friendly method.
  • Using NMR and vibrational spectroscopy shows that this method results in a simpler ionic structure compared to the traditional process involving PhMgCl and AlCl.
  • Tests on the electrochemical performance reveal that this new approach produces stable electrolytes, confirming its effectiveness.
View Article and Find Full Text PDF