Publications by authors named "A Subedi"
Chiral effects at the metal center in Fe(III) spin crossover coordination salts.
J Phys Condens Matter
January 2025
Evidence of chirality was observed at the Fe metal center in Fe(III) spin crossover coordination salts [Fe(qsal)][Ni(dmit)] and [Fe(qsal)](TCNQ)from x-ray absorption (XAS) spectroscopy at the Fe 2pcore threshold. Based on the circularly polarized XAS data, the x-ray natural circular dichroism for [Fe(qsal)][Ni(dmit)] and [Fe(qsal)](TCNQ)is far stronger than seen for [Fe(qsal)]Cl suggesting this natural circular dichroism signature is a ligand effect rather than a result of just a loss of octahedral symmetry on the Fe core. The larger the chiral effects in the Fe 2p core to bound XAS, the greater the perturbation of the Fe 2pto 2pspin-orbit splitting seen in the XAS spectra.
View Article and Find Full Text PDFIntroduction And Importance: Transverse testicular ectopia (TTE) is a rare congenital anomaly in which both testes descend into the same inguinal canal and are located in the same hemiscrotum. Diagnosing TTE can be challenging due to its rarity and unusual presentation.
Case Presentation: The authors present a case of a male in his 50s who was diagnosed with left transverse testicular ectopia after presenting with an empty right hemiscrotum and two testes-like masses in the left hemiscrotum.
Purpose: To evaluate and compare optical coherence tomography angiography (OCTA) retinal vasculature measurements in healthy, glaucoma suspect (GS), and glaucoma patients.
Methods: One hundred fourteen eyes with good quality OCTA pictures were included from 38 healthy, 38 GS, 38 and primary open-angle glaucoma (POAG) participants. The information on retinal vasculature was summarized as a vessel density map and as vessel density (%), which is the fraction of the flowing vessel area over the total area examined.
Article Synopsis
- * A case study involving a 79-year-old man with metastatic melanoma showed he experienced severe muscle weakness and elevated creatine kinase (CK) levels after treatment with ICIs, despite not presenting with muscle pain initially.
- * The patient's symptoms improved significantly after being treated with prednisone, which indicated that his condition was likely immune-related myositis triggered by the ICI therapy.
Introduction: We aimed to evaluate the relationship between preexisting chronic pain and acute postoperative pain after laparoscopic cholecystectomy (LC) and to identify predictors of acute postsurgery pain.
Methods: In this prospective cohort study, patients undergoing LC with general anesthesia were enrolled. The primary outcome was the incidence of moderate-to-severe pain during movement in the first 24 hours after surgery.