Though Pr doped LiYF (LiYF:Pr) bulk crystals are a well-known laser gain material with several radiative transitions, their nanocrystal counterparts have not been investigated with regards to these. Through downsizing to the nanoscale, novel applications are expected, especially in composite photonic devices. For example, nanocrystals in stable colloidal form with narrow size distribution are highly desirable to reduce scattering in such composites.
View Article and Find Full Text PDFNanomaterials (Basel)
July 2021
In recent years, optical nanothermometers have seen huge improvements in terms of precision as well as versatility, and several research efforts have been directed at adapting novel active materials or further optimizing the temperature sensitivity. The signal-to-noise ratio of the emission lines is commonly seen as the only limitation regarding high precision measurements. The role of re-absorption caused by a population of lower energy levels, however, has so far been neglected as a potential bottleneck for both high resolution and material selection.
View Article and Find Full Text PDFLanthanide-doped nanothermometers are used to measure temperature through changes in their emission characteristic with sensitivities of up to a few %/K. In contrast to their sensitivity, their spatial resolution, which is of critical importance for various applications, has not been thoroughly studied and optimized. We numerically investigated the improvement in spatial resolution of nanothermometers with a stimulated emission depletion microscopy approach.
View Article and Find Full Text PDFIn recent years, lanthanide-doped nanothermometers have been mainly used in thin films or dispersed in organic solvents. However, both approaches have disadvantages such as the short interaction lengths of the active material with the pump beam or complicated handling, which can directly affect the achievable temperature resolution. We investigated the usability of a polymer fiber doped with upconversion nanocrystals as a thermometer.
View Article and Find Full Text PDFWe demonstrate the controllable generation of infrared dispersive waves (DWs) from customized, in-house fabricated silica microstructured optical fibers (MOFs) by manipulating the location of zero dispersion wavelength (ZDW) through the structure of the fibers. The highly enriched shaping mechanism of arrested soliton in the MOFs with two ZDWs provides a technique for efficient energy transfer into the targeted eye-safe wavelengths at 1.7 and 2.
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