Mono-β-diketonate Metal Complexes of the First Transition Series.

Mono-β-diketonate compounds have been fleetingly observed in base metal catalyzed reactions, which are of current interest as alternatives to precious metal catalyzed reactions. Their isolation has been challenging due to synthetic and structural limitations of acac-type ligands, leading to the development of a related NacNac ligand platform. Herein we report the synthesis of a β-diketone capable of kinetically stabilizing relevant catalytic intermediates.

Preparation of Single-cell Suspension of Mouse Thymic Epithelial Cells and Staining of Intracellular Molecules for Flow Cytometric Analysis.

Thymic epithelial cells (TECs) play an essential role in promoting the development and repertoire selection of T cells. Cortical TECs (cTECs) in the thymic cortex induce early T cell development and positive selection of cortical thymocytes. In contrast, medullary TECs (mTECs) in the thymic medulla attract positively selected thymocytes from the cortex and establish self-tolerance in T cells.

Calibration by Proxy.

Calibration by Proxy (CbPx) is a matrix-matched calibration method that utilizes multiple internal standard species to build a calibration curve. The technique requires only two solutions: solution 1 containing a sample solution and a suite of internal standards at known concentrations, and solution 2 identical to solution 1, plus an aliquot of a standard containing all analytes and the internal standards at the same concentration. The calibration curve is prepared by plotting the signal measured for each internal standard in solution 1 divided by the signal arising due to the aliquot of internal standard added to solution 2 on the -axis.

'I like you so . . . ': how transgressor and interviewer likeability and familiarity influence children's disclosures.

This study examined how children's age and their ratings of the likeability of a transgressor (E1) and an interviewer (E2) influenced their testimonies after witnessing a theft. Children ( = 152; ages 7-13 years) witnessed E1 steal $20 from a wallet. E1 then asked the children to lie and say that they did not take the money.