Assessment of global carbon dynamics due to mining-induced forest cover loss during 2000-2019 using satellite datasets.

Mining activities significantly contribute to forest cover loss (FCL), subsequently altering global carbon dynamics and exacerbating climate change. The present study aims to estimate the contributions of mining-induced FCL to carbon sequestration loss (CSL) and carbon dioxide (CO₂) emissions from 2000 to 2019 using the proxy datasets. For FCL analysis, the global FCL data at 30 m spatial resolution, developed by Hansen et al.

A cross-shaped terahertz metamaterial absorber for brain cancer detection.

The article presents, for the first time, a terahertz metamaterial absorber (TMA) designed in the shape of a cross consisting of four orthogonally positioned horn-shaped patches in succession, to detect brain cancer cells. The design exhibits the property of mu-negative material, indicating magnetic resonance. The proposed TMA has achieved an impressive absorption rate of 99.

Selective Transfer Hydrogenation of C=O and Conjugated C=C Bonds Using An NHC-Based Pincer (CNC)Mn Complex in Methanol.

Base metal catalyzed transfer hydrogenation reactions using methanol is highly challenging. Employing a single N-heterocyclic carbene (NHC)-based pincer (CNC)Mn complex, chemoselective single and double transfer hydrogenation of α, β-unsaturated ketones to saturated ketones or alcohols by utilizing methanol as the hydrogen source is disclosed. The protocol was tolerant towards the selective transfer hydrogenation of C=C or C=O bonds in the presence of several other reducible functional groups and led to the synthesis of several biologically relevant molecules and natural products.

Diastereoselective reversible C-C bond exchange of oxindole-thiazolidienediones for dynamic combinatorial chemistry.

We herein describe a diastereoselective aldol exchange involving isatins and thiazolidinediones, providing oxindolyl-thiazolidienediones in aqueous media at pH 6. This equilibrium can also be achieved with oxindole exchange as well as cross-exchange within reasonable timescales. These metal and organic catalyst free reversible reactions provide a unique opportunity for the evolution of dynamic combinatorial libraries (DCLs) for target directed dynamic combinatorial chemistry (DCC) and system chemistry.

Thiazole Containing PNA Mimic Regulates Gene Expression through DNA G-Quadruplex.

Peptide nucleic acids (PNAs), besides hybridizing to complementary DNA and RNAs, bind and stabilize DNA secondary structures. Herein, we illustrate the design and synthesis of PNA-like scaffolds by incorporating five-membered thiazole rings as modified bases instead of nucleobases and their subsequent effects on gene regulation by biophysical and assays. A thiazole-modified PNA trimer selectively recognizes G-quadruplex (G4) DNA over other G4s and duplex DNA.