Effective protection of groundwater requires an accurate health risk assessment of contaminants; however, the diversity of pollution sources, variability, and uncertainties in exposure parameters present significant challenges in this assessment. In this study, groundwater risk estimates associated with NO, and F, along with fourteen heavy metal(loid)s (V, Cr, Mn, Fe, Ni, Cu, As, Co, Cd, Se, Pb, Hg, Zn, and Al) in an agricultural area were optimized by implementing positive matrix factorization (PMF), multilinear regression, and two-dimensional Monte Carlo simulations to characterize source-specific health risks. Groundwater pollution was analyzed considering regional variations, including differences in elevation, land use and land cover, and soil types.
View Article and Find Full Text PDFA rapid and efficient ultrasound-assisted extraction (UAE) procedure followed by inductively coupled plasma mass spectrometry (ICP-MS) was developed for the determination of 14 rare earth elements (REEs) (La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu), along with yttrium (Y) and scandium (Sc), in coffee samples. The method was validated using certified reference material (NIST SRM 1547), recovery tests at four fortification levels, and comparisons with microwave-assisted digestion (MAD). Excellent accuracy and precision were achieved, with recovery rates ranging from 80.
View Article and Find Full Text PDFChocolate is one of the most popular and widely consumed confectionery products. However, elevated cadmium (Cd) content in this commodity threatens food safety and human health. It is crucial to monitor the presence of Cd in chocolate and to evaluate its associated health risks.
View Article and Find Full Text PDFHuman activities have far-reaching impact on natural ecosystems, causing increasing disturbances and disruptions to the delicate balance of the environment. Poor land use planning, urbanization, infrastructure development, and unplanned tourism exacerbate contamination and degradation in tourist destinations, yet the pollution of potentially toxic elements (PTEs) in these environments remains inadequately explored. To address this issue, we investigated the concentrations of acid-digested PTEs in road dust in Abbottabad city (Pakistan) with heavy traffic.
View Article and Find Full Text PDFThis study incorporated hydrogeochemical facies, the entropy-weighted water quality index (EWQI), multivariate statistics, and probabilistic human exposure assessment to investigate hydrogeochemistry, analyze groundwater quality, and estimate potential risks to human health in a lithium-rich ore area (Jadar River basin, Serbia). The findings designated the Ca·Mg-HCO hydrogeochemical type as the predominant type of groundwater, in which rock weathering and evaporation control the major ion chemistry. Due to the weathering of a lithium-rich mineral (Jadarite), the lithium content in the groundwater was very high, up to 567 mg/L, with a median value of 4.
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