Ligand-Induced Intramolecular Cuprophilic and Argentophilic Interactions in Bimetallic Cu(I) and Ag(I) Phosphine Complexes and the Assessment of Their Antityrosinase and Antibacterial Effects.

Binuclear silver(I) and copper(I) complexes, and , with bridging diphenylphosphine ligands were prepared. In , the silver(I) center is located inside a trigonal plane composed of three phosphorus donors from three separate and bridging dppm ligands. The fourth coordination site is filled with neighboring silver(I) ions.

Stable homogeneous silver(I) catalysts for the highly efficient cycloaddition of azides onto terminal alkynes in water.

To develop stable and efficient silver(I) catalysts and evaluate the role of sulfur and phosphorus donor ligands in the catalytic cycloaddition of selected organic azides and alkynes (AAC), a series of mononuclear Ag(I) and heteronuclear Ag(I)-Fe(II) complexes were synthesized. The synthesis utilized phosphine and sulfur donors from the dialkyldithiophosphate and borate families, specifically Na[SH2B(mt)]. These complexes are designated as [(dppf)AgSP(S)(OPr)] (1), [SHB(mt)Ag(μ-dppf)AgSHB(mt)] (2), [(dppf)Ag(μ-dppf)Ag(dppf)] (3), and [(dppe)AgSHB(mt)] (5).

Patient's airway monitoring during cardiopulmonary resuscitation using deep networks.

Cardiopulmonary resuscitation (CPR) is a crucial life-saving technique commonly administered to individuals experiencing cardiac arrest. Among the important aspects of CPR is ensuring the correct airway position of the patient, which is typically monitored by human tutors or supervisors. This study aims to utilize deep transfer learning for the detection of the patient's correct and incorrect airway position during cardiopulmonary resuscitation.

Introducing Novel Redox-Active Bis(phenolate) N-Heterocyclic Carbene Proligands: Investigation of Their Coordination to Fe(II)/Fe(III) and Their Catalytic Activity in Transfer Hydrogenation of Carbonyl Compounds.

A simple and efficient procedure for synthesizing novel pincer-type tridentate N-heterocyclic carbene bisphenolate ligands is reported. The synthesis of pincer proligands with ,'-disubstituted imidazoline core, and , was carried out via triethylorthoformate-promoted cyclization of either ,'-bis(2-hydroxy-3,5-di--butylphenyl)cyclohexanediamine, , or ,'-bis(2-hydroxyphenyl)cyclohexanediamine, , in the presence of concentrated hydrochloric acid. Cyclic voltammograms of the ligands revealed ligand-centered redox activity, indicating the noninnocent nature of the ligands.

Projections of meteorological drought severity-duration variations based on CMIP6.

This research utilized the outputs from three models of the Coupled Model Intercomparison Project Phase 6 (CMIP6), specifically CanESM5, GFDL-ESM4, and IPSL-CM6A-LR. These models were used under the SSP1-2.6 and SSP5-8.