Photoelectron emission microscopy (PEEM) and low energy electron microscopy (LEEM) can easily distinguish between organic molecules adsorbed in crystallites or in the wetting layers as well as the bare metal substrate due to their different electronic properties. Already before (and during) the condensation of such solid phases (2D islands or 3D crystallites), there is a dilute 2D gas phase. Such a 2D gas phase consists of molecules, which are highly mobile and diffuse across the surface.
View Article and Find Full Text PDFWe present a compact in situ electromagnet with an active cooling system for use in ultrahigh vacuum environments. The active cooling enhances the thermal stability and increases the electric current that can be applied through the coil, promoting the generation of homogeneous magnetic fields, required for applications in real-time deposition experiments. The electromagnet has been integrated into a reflectance difference magneto-optic Kerr effect (RD-MOKE) spectroscopy system that allows the synchronous measurement of the optical anisotropy and the magneto-optic response in polar MOKE geometry.
View Article and Find Full Text PDFIn the Fe-doped GaN phase-separated magnetic semiconductor Ga[Formula: see text]FeN, the presence of embedded [Formula: see text]-[Formula: see text]N nanocrystals determines the magnetic properties of the system. Here, through a combination of anomalous X-ray diffraction and diffraction anomalous fine structure, the local structure of Ga in self-assembled face-centered cubic (fcc) [Formula: see text]-[Formula: see text]N nanocrystals embedded in wurtzite GaN thin layers is investigated in order to shed light onto the correlation between fabrication parameters, local structural arrangement and overall magnetic properties of the material system. It is found, that by adjusting the growth parameters and thus, the crystallographic surroundings, the Ga atoms can be induced to incorporate into 3c positions at the faces of the fcc crystal lattice, reaching a maximum occupancy of 30%.
View Article and Find Full Text PDFPhase-separated semiconductors containing magnetic nanostructures are relevant systems for the realization of high-density recording media. Here, the controlled strain engineering of Ga δ FeN layers with Fe y N embedded nanocrystals (NCs) Al x Ga 1 - x N buffers with different Al concentration 0 < x Al < 41 % is presented. Through the addition of Al to the buffer, the formation of predominantly prolate-shaped ε -Fe 3 N NCs takes place.
View Article and Find Full Text PDFJ Phys Chem C Nanomater Interfaces
June 2018
Perfluoropentacene (PFP) is an organic material that has been widely studied over the last years and has already found applications in organic electronics. However, fundamental physical questions, such as the structural formation and the preferential orientation of the molecules during deposition on metal surfaces, are still not fully understood. In this work, we report on a unique in-plane molecular reorientation during the completion of the first monolayer of PFP on the Ag(110) surface.
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