Adjusting the Architecture of Heptagonal Metallo-Macrocycles by Embedding Metal Nodes into the Backbone.

Coordination-driven self-assembly has been extensively employed for the bottom-up construction of discrete metallo-macrocycles. However, the prevalent use of benzene rings as the backbone limits the formation of large metallo-macrocycles with more than six edges. Herein, by embedding metal nodes into the ligand backbone, we successfully regulated the ligand arm angle and assembled two giant heptagonal metallo-macrocycles with precise control.

Management of Pea Leaf Weevil (Coleoptera: Curculionidae) and Development of a Nominal Threshold in Faba Beans.

Pea leaf weevil, Sitona lineatus (L.) (Coleoptera: Curculionidae), can reduce the yield of field pea [Pisum sativum (L.) (Fabales: Fabaceae)] and faba bean [Vicia faba (L.