[Calculation of the intrinsic viscosity of synthetic and biological polyelectrolytes of various rigidity].

On the basis of the excluded-volume effect theory for nonionic polymer molecules developed by Alexandrowicz semi-empirical formulas for calculation of the intrinsic viscosity [eta] of polyelectrolytes of various rigidity are proposed. The expression for the second virial coefficient of gas consisting of cylindrical particles is used for the determination of explicit form of the effective excluded volume of the segment upsilon0. In addition the alteration of Flory's parameter phi (epsilon) by the expansion of a macromolecule, and the alteration of thermodynamic rigidity A of the polyelectrolyte molecule in the range of low ionic strengths mu have been taken into account.