Bridging 1,2-Bis(diphenylphosphino)methane Ligands Facilitate the Formation of Binuclear Complexes with Both Two-Coordinate and Three-Coordinate Gold(I) Ions.

Five new crystalline gold(I) complexes β-Au(μ-dppm)Br·2CHCl (), [Au(μ- dppm)Br]Br·2CHCl (), [Au(μ-dppm)Br](PF) (), [Au(μ-dppm)Cl](BPh)·3CHCl () and [Au(μ-dppm)]Cl(AsF)·2CHCl () (where dppm is bis(diphenylphosphino)methane) have been prepared and structurally characterized by single crystal X-ray diffraction. Colorless β-Au(μ-dppm)Br·2CHCl () has centrosymmetric structure with two three-coordinate gold(I) ions held in close proximity by the dppm ligands. Crystals of [Au(μ- dppm)Br]Br·2CHCl (), [Au(μ-dppm)Br](PF) (), and [Au(μ-dppm)Cl](BPh)·3CHCl () have a cation with an unusual arrangement that binds a two-coordinate gold(I) ion to a three-coordinate gold(I) ion through an aurophilic interaction.

Results of a Pilot Trial Assessing the Effects of Proper Oral Hygiene and a Probiotic Dietary Supplement on Oral Health in Volunteers with Oral Malodor.

Persistent malodor affects many people worldwide and is usually associated with poor dental hygiene. This pilot trial aimed to determine whether proper dental hygiene (DH) and a probiotic dietary supplement support oral health in volunteers with persistent malodor. Volunteers ( = 35) were randomly assigned to the probiotic or placebo cohort.

Molecular Flexibility in Solvated Crystals of the Dimer, Au(μ-1,2-bis(diphenylphosphino)ethane)I, with Three-Coordinate Gold(I).

We report the ability to trap the dimer Au(μ-dppe)I (dppe is 1,2-bis(diphenylphosphino)ethane) with different separations between the three-coordinate gold ions in crystalline solvates. All of these solvates ((Au(μ-dppe)I·4(CHCl) (), Au(μ-dppe)I·2(CHCl) (), the polymorphs α-Au(μ-dppe)I·2(HC(O)NMe) () and β-Au(μ-dppe)I·2(HC(O)NMe) (), and Au(μ-dppe)I·4(CHCl) ()) along with polymeric {Au(μ-dppe)I}·(CHCl) ()) originated from the same reaction, only the solvent system used for crystallization differed. In the different solvates of Au(μ-dppe)I, the Au···Au separation varied from 3.

Covalently linked thieno[2,3-]thiophene-fullerene dimers: synthesis and physical characterization.

Thienothiophene (TT) has received great attention in the fields of electronics and optoelectronics. Here we report a synthesis and characterization of fullerene-donor-fullerene triads linked to thieno[2,3-]thiophene as a donor. The photophysical and electrochemical properties of the new dumbbells were investigated using UV-vis spectroscopy, fluorescence spectroscopy, cyclic voltammetry, and square wave voltammetry.

Open-cage fullerenes as ligands for metals.

The remarkable structures of open-cage fullerenes with functionalization on the outer surface and an accessible inner void make them interesting ligands for reactions with metal complexes. The behaviors of open-cage fullerenes in reactions with various metal complexes are examined and compared to the corresponding reactions with intact fullerenes. The structural results from X-ray diffraction are emphasized.