Mesoscale self-organization of polydisperse magnetic nanoparticles at the water surface.

In this study, we investigated the self-ordering process in Langmuir films of polydisperse iron oxide nanoparticles on a water surface, employing in situ x-ray scattering, surface pressure-area isotherm analysis, and Brewster angle microscopy. X-ray reflectometry confirmed the formation of a monolayer, while grazing incidence small-angle x-ray scattering revealed short-range lateral correlations with a characteristic length equal to the mean particle size. Remarkably, our findings indicated that at zero surface pressure, the particles organized into submicrometer clusters, merging upon compression to form a homogeneous layer.

Trustable Environmental Monitoring by Means of Sensors Networks on Swarming Autonomous Marine Vessels and Distributed Ledger Technology.

The article describes a highly trustable environmental monitoring system employing a small scalable swarm of small-sized marine vessels equipped with compact sensors and intended for the monitoring of water resources and infrastructures. The technological foundation of the process which guarantees that any third party can not alter the samples taken by the robot swarm is based on the Robonomics platform. This platform provides encrypted decentralized technologies based on distributed ledger tools, and market mechanisms for organizing the work of heterogeneous multi-vendor cyber-physical systems when automated economical transactions are needed.

Substantial Difference in Ordering of 10, 15, and 20 nm Iron Oxide Nanoparticles on a Water Surface: In Situ Characterization by the Grazing Incidence X-ray Scattering.

In the present study, for the first time, a unique combination of in situ grazing incidence small-angle X-ray scattering and X-ray reflectivity, accompanied by the pressure-area isotherm analysis, Brewster angle microscopy, and ex situ scanning electron microscopy, was applied for investigation of two-dimensional superlattices of magnetic nanoparticles as they form on a water surface in a Langmuir trough. Iron oxide particles of different sizes stabilized with a single layer of oleic acid were used. It is demonstrated that monodisperse 10 nm particles on a water surface reproducibly form identical highly ordered monolayers in a wide range of experimental conditions, while monodisperse 20 nm particles always form compact three-dimensional clusters and never the monolayers.

Structural investigations of self-assembled monolayers for organic electronics: results from X-ray reflectivity.

Self-assembled monolayers (SAMs) have been established as crucial interlayers and electronically active layers in organic electronic devices, such as organic light emitting diodes (OLEDs), organic photovoltaics (OPVs), organic thin film transistors (OTFTs), and nonvolatile memories (NVMs). The use of self-assembling functionalized organic molecules is beneficial due to mainly three advantages compared with common thin film deposition approaches. (1) Molecular self-assembly occurs with surface selectivity, determined by the interaction between the functional anchor group of the organic molecules and the target surface.

Tuning the molecular order of C60-based self-assembled monolayers in field-effect transistors.

The control of order in organic semiconductor systems is crucial to achieve desired properties in electronic devices. We have studied the order in fullerene functionalized self-assembled monolayers by mixing the active molecules with supporting alkyl phosphonic acids of different chain length. By adjusting the length of the molecules, structural modifications of the alignment of the C60 head groups within the SAM can be tuned in a controlled way.