Understanding the Nature of Vibro-Polaritonic States in Water and Heavy Water.

Very recent experiments on vibrational strong coupling tend to modify chemical reactivity, energy transfer, and many other physical properties of the coupled system. This is achieved without external stimuli and is very sensitive to the vibrational envelope. Water is an excellent vibrational oscillator, which is being used for similar experiments.

Boosting Self-interaction of Molecular Vibrations under Ultrastrong Coupling Condition.

In this letter, we investigated the modification of the oscillator strength of an asymmetric stretching band of CS by strong coupling to an infrared cavity photon. This is achieved by placing liquid CS in a Fabry-Perot resonator and tuning the cavity mode position to match the molecular vibrational transition. Ultrastrong coupling leads to an increase in the effective oscillator strength of the asymmetric stretching band of CS.

Photophysical Behavior and Fluorescence Quenching of l-Tryptophan in Choline Chloride-Based Deep Eutectic Solvents.

Intrinsic fluorescence from l-tryptophan (l-Trp) is routinely used to obtain insight into the structural features and dynamics of proteins and enzymes. In contrast to aqueous enzymology, different parameters that control and influence the behavior of proteins and enzymes in nonaqueous media depend heavily on the solvent. Detailed analysis of the intrinsic fluorescence from l-Trp dissolved in two deep eutectic solvents (DESs), reline and glyceline, prepared by mixing salt choline chloride with H-bond donors urea and glycerol, respectively, in a 1:2 molar ratio within 298.

Probing interactions within liquid media via a model H-bond donor-acceptor mixture.

Understanding interactions within liquids so as to obtain desired physicochemical properties is of utmost importance in chemistry. Solute-solvent and solvent-solvent interactions within mixtures of hexamethylphosphoramide (HMPA) and 2,2,2-trifluoroethanol (TFE) are assessed using various invasive and non-invasive techniques. HMPA and TFE possess similar static dielectric constants.