Searching for stable copper borozene complexes in CuB and CuB.

Copper has been shown to be an important substrate for the growth of borophenes. Copper-boron binary clusters are ideal platforms to study the interactions between copper and boron, which may provide insight about the underlying growth mechanisms of borophene on copper substrates. Here we report a joint photoelectron spectroscopy and theoretical study on two copper-doped boron clusters, CuB and CuB.

Ionic Liquid as a N,O-Donor Ligand-Based Extraction System Modifier: Establishing the Mechanism of Am(III)-Selectivity Increasing.

In this work, we studied the extraction systems for the separation -elements based on the tetradentate N,O-donor ligand di(-ethyl-4-ethylanilide) 2,2'-dipyridyl-6,6'-dicarboxylic acid (). The organic phase of these systems was perspective fluorine-containing organic solvents-metanitrobenzotrifluoride (), ionic liquid CmimNTf (), and their mixture. The increase of Am(III) selectivity in the presence of Ln(III) in cases of the diluent mixture was shown.

Kinetic features of solvent extraction by N,O-donor ligands of f-elements: a comparative study of diamides based on 1,10-phenanthroline and 2,2'-bipyridine.

A variant of microfluidic setup design for the study of extraction kinetics has been proposed. Mass transfer constants for Am(III) and Eu(III) and observed rate constants were obtained for N-,O-donor ligands featuring phenanthroline and bipyridyl cores. The possibility of determining rate constants for cations independently of each other makes it possible to observe the kinetic effect of separation.

Sensing and extraction of hazardous metals by di-phosphonates of heterocycles: a combined experimental and theoretical study.

In this study, pyridine and phenanthroline diphosphonate ligands were investigated for the first time from the context of solvent extraction and potentiometric sensing of Co(II), Ni(II), Cu(II), Zn(II), Cd(II), and Pb(II) cations. The extraction efficiency under the same conditions for phenanthroline-diphosphonates is considerably higher than that for pyridine ligands. At the same time, the pyridine-diphosphonates show pronounced selectivity towards lead in this metal series.

Bismuth Infrared Star: Being at a Glance.

Bismuth polycations have garnered significant attention from researchers due to their extraordinary and counter-intuitive structures and stoichiometries. Despite extensive experimental and theoretical investigations, understanding of the bonding in such clusters remains insufficient. An AdNDP bonding analysis was conducted to elucidate the bonding characteristics using both homoatomic and heteroatomic bismuth clusters with various stoichiometries.