Publications by authors named "A I Kulak"

Article Synopsis
  • - The compound polycrystalline [FeL2][BF4]2 demonstrates a significant hysteretic spin transition around 240 K, with its behavior influenced by sample history, consisting of two related high-spin polymorphs (HS1 and HS2).
  • - Upon cooling, both high-spin forms transition to low-spin phases (LS3 and LS4) at approximately 230 K, with LS3 coming from HS1 and LS4 from HS2, showing different crystal structures and transition temperatures.
  • - Repeated cycling through the spin transition results in a gradual increase of HS1 and LS3 phases while depleting HS2 and LS4, indicating complex phase behavior and sample-dependent characteristics across related iron(II) and
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Objectives: Evidence suggests that decreased dopamine secretion in mesocorticolimbic pathways could predispose to increased susceptibility to substance addiction. It has been proposed to define such a phenomenon as the reward deficit syndrome (RDS). Dopaminergic projections of the reward system receive glutaminergic projections from cortex.

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A key factor in biomineralization is the use of organic molecules to direct the formation of inorganic materials. However, identification of molecules that can selectively produce the calcium carbonate polymorphs calcite or aragonite has proven extremely challenging. Here, we use a phage display approach to identify proteins - rather than the short peptides typically identified using this method - that can direct calcium carbonate formation.

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Ultrahigh-temperature Joule-heating of carbon nanostructures opens up unique opportunities for property enhancements and expanded applications. This study employs rapid electrical Joule-heating at ultrahigh temperatures (up to 3000 K within 60 s) to induce a transformation in nanocarbon aerogels, resulting in highly graphitic structures. These aerogels function as versatile platforms for synthesizing customizable metal oxide nanoparticles while significantly reducing carbon emissions compared to conventional furnace heating methods.

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The residual bone tumor and defects which is caused by surgical therapy of bone tumor is a major and important problem in clinicals. And the sequential treatment for irradiating residual tumor and repairing bone defects has wildly prospects. In this study, we developed a general modification strategy by gallic acid (GA)-assisted coordination chemistry to prepare black calcium-based materials, which combines the sequential photothermal therapy of bone tumor and bone defects.

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